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DC Field | Value | Language |
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dc.contributor.author | Sánchez-Sala, M. | - |
dc.contributor.author | Pons, Josefina | - |
dc.contributor.author | Alvarez-Larena, A. | - |
dc.contributor.author | Bayés-García, Laura | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Ayllón, J. A. | - |
dc.date.accessioned | 2020-05-18T07:27:15Z | - |
dc.date.available | 2020-12-31T06:10:21Z | - |
dc.date.issued | 2018 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/2445/160805 | - |
dc.description.abstract | The complexes [Cu(PhOBz)2(dPy)]2 (PhOBz = 4-phenoxybenzoate; dPy = pyridine (1), 3-phenylpyridine (2), 4-benzylpyridine (3) and 4-phenylpyridine (4) and the complex [Cu(PhOBz)2(4-Phpy)2(H2O)] (5) were prepared and fully characterized. X-ray crystal structures of the five complexes have been determined. Complexes 1-4 consist of binuclear units where both Cu(II) are linked by four syn-syn carboxylate bridges, showing a paddle-wheel unit. The compound 5 is mononuclear and the metal center is coordinated to two PhOBz in monodentate form, two 4-Phpy ligands and one H2O molecule with slightly distorted square pyramidal geometry. Finally, the magnetic properties of compounds 3 and 5 have also been studied, confirming the different strength interactions between Cu(II) cations. | - |
dc.format.extent | 29 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2018.06.015 | - |
dc.relation.ispartof | Polyhedron, 2018, vol. 151, p. 545-553 | - |
dc.relation.uri | https://doi.org/10.1016/j.poly.2018.06.015 | - |
dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2018 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Cristal·lografia | - |
dc.subject.classification | Coure | - |
dc.subject.other | Crystallography | - |
dc.subject.other | Copper | - |
dc.title | Cu(II) 4-phenoxybenzoate dimers and monomer coordinated by pyridines: synthesis and crystal structures | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 685525 | - |
dc.date.updated | 2020-05-18T07:27:16Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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685525.pdf | 1.73 MB | Adobe PDF | View/Open |
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