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http://hdl.handle.net/2445/161362
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DC Field | Value | Language |
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dc.contributor.author | Sánchez-Férez, Francisco | - |
dc.contributor.author | Soldevila-Sanmartín, Joan | - |
dc.contributor.author | Ayllón, J. A. | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Furdada i Bellavista, Glòria | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2020-05-19T15:33:48Z | - |
dc.date.available | 2021-05-15T05:10:22Z | - |
dc.date.issued | 2019-05-15 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/2445/161362 | - |
dc.description.abstract | Three different paddle wheel compounds have been synthesized, each one via a different synthetic pathway. The first method is the reaction of Cu(MeCO2)2 H2O with 1,3-benzodioxole-5-carboxylic acid (Piperonylic acid, HPip) in a MeOH solution, yielding [Cu(m-Pip)2(MeOH)]2 (1). The second method is the transformation of the heteroleptic core paddle-wheel compound [Cu(m-MeCO2)(m-Pip)(MeOH)]2 into the homoleptic core paddle-wheel [Cu(m-Pip)2(DMSO)]2 2DMSO (2). Lastly, the third method is the substitution of the solvent molecule (DMF) present in the molecular array [Cu(m-Pip)2(DMF)]2 by 2-benzylpyridine (2-Bzpy) ligand, resulting in [Cu(m-Pip)2(2-Bzpy)]2 2.5MeOH H2O (3a). All compounds are characterized via EA, PXRD, ATR-FTIR, Far-IR and UV-Vis spectroscopy. For all three compounds, the X-ray crystal structure has been determined and their extended structures are discussed. Finally, TG/DTA measurements have been recorded. | - |
dc.format.extent | 29 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2019.02.036 | - |
dc.relation.ispartof | Polyhedron, 2019, vol. 164, p. 64-73 | - |
dc.relation.uri | https://doi.org/10.1016/j.poly.2019.02.036 | - |
dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2019 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.other | Layer structure (Solids) | - |
dc.title | Synthesis and characterization of three new Cu(II) paddle-wheel compounds with 1,3-benzodioxole-5-carboxylic acid | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 691693 | - |
dc.date.updated | 2020-05-19T15:33:49Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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File | Description | Size | Format | |
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691693.pdf | 1.17 MB | Adobe PDF | View/Open |
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