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https://hdl.handle.net/2445/161561
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DC Field | Value | Language |
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dc.contributor.author | Mayans Ayats, Júlia | - |
dc.contributor.author | Martin, Anna | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Escuer Fité, Albert | - |
dc.date.accessioned | 2020-05-20T08:34:01Z | - |
dc.date.available | 2020-12-31T06:10:21Z | - |
dc.date.issued | 2018 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | https://hdl.handle.net/2445/161561 | - |
dc.description.abstract | Chiral tetranuclear clusters have been obtained employing enantiomerically pure Schiff bases and azido coligands. The core of the new clusters shows defective dicubane topology with two vertices occupied by two l1,1,1-N3 ligands. Linkage between the NiII cations is completed with two l-O(phenoxo) and two l-Cl bridging ligands. The new systems have been characterized by single crystal X-ray analysis, electronic circular dichroism and susceptibility/magnetization measurements that reveal ferromagnetic response and strong positive zero field splitting of the S = 4 ground state. | - |
dc.format.extent | 21 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier Ltd | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.poly.2018.05.002 | - |
dc.relation.ispartof | Polyhedron, 2018, vol. 150, p. 10-14 | - |
dc.relation.uri | https://doi.org/10.1016/j.poly.2018.05.002 | - |
dc.rights | cc-by-nc-nd (c) Elsevier Ltd, 2018 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Níquel | - |
dc.subject.classification | Magnetisme | - |
dc.subject.classification | Dicroisme circular | - |
dc.subject.other | Nickel | - |
dc.subject.other | Magnetism | - |
dc.subject.other | Circular dichroism | - |
dc.title | Chiral tetranuclear NiII clusters derived from Schiff bases and azido co-ligands. | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 684658 | - |
dc.date.updated | 2020-05-20T08:34:01Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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File | Description | Size | Format | |
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684658.pdf | 1.29 MB | Adobe PDF | View/Open |
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