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http://hdl.handle.net/2445/162028
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DC Field | Value | Language |
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dc.contributor.author | Ejarque, Daniel | - |
dc.contributor.author | Sánchez-Férez, Francisco | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2020-05-22T10:20:13Z | - |
dc.date.available | 2022-09-01T05:10:18Z | - |
dc.date.issued | 2020-09-01 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | http://hdl.handle.net/2445/162028 | - |
dc.description.abstract | The synthesis and characterization of four new coordination complexes is presented. Two of them have been obtained by reaction between M(OAc)2·2H2O (M= Zn(II), Cd(II)) and α-acetamidocinnamic acid (HACA) yielding two isostructural monomeric compounds with general formula [M(ACA)2(H2O)2] (M=Zn(II) (1), Cd(II) (2)). In opposite, the reactivity of 1 and 2 with 4-phenylpyridine (4-Phpy) leads to a monomeric [Zn(4-Phpy)2(ACA)2(H2O)2]·3H2O (3) or a dimeric compound [Cd(4-Phpy)2(µ-ACA)(ACA)]2·2EtOH (4). All of them have been characterised by analytical and spectroscopic techniques. In addition, single crystals of 1-4 for X-ray diffraction analysis have been obtained and their intra- and intermolecular interactions have been discussed and studied by Hirshfeld surface analysis, showing 3D supramolecular networks for all the compounds. In addition, the thermal stability of 3 and 4 has been studied. Finally, the photoluminescence properties of 1-4 have been examined, and their quantum yields calculated. | - |
dc.format.extent | 39 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.ica.2020.119695 | - |
dc.relation.ispartof | Inorganica Chimica Acta, 2020, vol. 509, p. 119695 | - |
dc.relation.uri | https://doi.org/10.1016/j.ica.2020.119695 | - |
dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2020 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Radiocristal·lografia | - |
dc.subject.classification | Compostos metàl·lics | - |
dc.subject.classification | Química organometàl·lica | - |
dc.subject.other | X-ray crystallography | - |
dc.subject.other | Metallic composites | - |
dc.subject.other | Organometallic chemistry | - |
dc.title | Exploring the Reactivity of α-Acetamidocinnamic Acid and 4-Phenylpyridine with Zn(II) and Cd(II) | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 700925 | - |
dc.date.updated | 2020-05-22T10:20:13Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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700925.pdf | 1.93 MB | Adobe PDF | View/Open |
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