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Title: Decanuclear FeIII clusters with hemiacetal ligands: a new{M10(μ3-O)8} cluster core
Author: Mayans Ayats, Júlia
Roc, L.
Font Bardia, Ma. Mercedes
Escuer Fité, Albert
Keywords: Lligands (Bioquímica)
Compostos organometàl·lics
Ligands (Biochemistry)
Organometallic compounds
Issue Date: 1-Jul-2019
Publisher: Royal Society of Chemistry
Abstract: The characterization of a decanuclear FeIII cluster with α-methyl- 2-pyridinemethanolate, generated by the hydrolysis of Schiff bases, inspired us to carry out an initial exploration of the direct syntheses of medium nuclearity FeIII clusters starting from aldehydes in methanolic medium. The new complexes exhibit an unprecedented {Fe10(μ3-O)8} cluster core.
Note: Versió postprint del document publicat a:
It is part of: Journal of the Chemical Society, Dalton Transactions, 2019, vol. 48, num. 35, p. 13139-13142
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ISSN: 1472-7773
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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