Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/162672| Title: | Chiral [MnIIMnIII3M'] (M' = NaI, CaII, MnII) and [MnIIMnIII6NaI2] clusters built from an enantiomerically pure Schiff base: synthetic, chiroptical and magnetic properties |
| Author: | Mayans Ayats, Júlia Bardia, Ma. Mercedes Di Bari, Lorenzo Górecki, M. Escuer Fité, Albert |
| Keywords: | Quiralitat Propietats magnètiques Manganès Chirality Magnetic properties Manganese |
| Issue Date: | 1-Sep-2018 |
| Publisher: | Wiley-VCH |
| Abstract: | From the reaction of manganese halides with the chiral Schiff bases obtained by condensation of o-vanillin and (R)- or (S)-phenylglycinol, 11 complexes based on pentanuclear cages with trigonal bipyramidal [MnIIMnIII3M'] (M'=NaI, CaII, MnII) or enneanuclear [MnIIMnIII6NaI2] cores were synthesized. Structural, supramolecular chirality, and optical properties were explored. The magnetic properties of related systems were reviewed, and the magnetic response of the new systems was rationalized to the bond parameters. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1002/chem.201803730 |
| It is part of: | Chemistry-A European Journal, 2018, vol. 24, p. 18705-18717 |
| URI: | http://hdl.handle.net/2445/162672 |
| Related resource: | https://doi.org/10.1002/chem.201803730 |
| ISSN: | 0947-6539 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 684194.pdf | 2.13 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.