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Title: Chiral [MnIIMnIII3M'] (M' = NaI, CaII, MnII) and [MnIIMnIII6NaI2] clusters built from an enantiomerically pure Schiff base: synthetic, chiroptical and magnetic properties
Author: Mayans Ayats, Júlia
Bardia, Ma. Mercedes
Di Bari, Lorenzo
Górecki, M.
Escuer Fité, Albert
Keywords: Quiralitat
Propietats magnètiques
Magnetic properties
Issue Date: 1-Sep-2018
Publisher: Wiley-VCH
Abstract: From the reaction of manganese halides with the chiral Schiff bases obtained by condensation of o-vanillin and (R)- or (S)-phenylglycinol, 11 complexes based on pentanuclear cages with trigonal bipyramidal [MnIIMnIII3M'] (M'=NaI, CaII, MnII) or enneanuclear [MnIIMnIII6NaI2] cores were synthesized. Structural, supramolecular chirality, and optical properties were explored. The magnetic properties of related systems were reviewed, and the magnetic response of the new systems was rationalized to the bond parameters.
Note: Versió postprint del document publicat a:
It is part of: Chemistry-A European Journal, 2018, vol. 24, p. 18705-18717
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ISSN: 0947-6539
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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