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Title: Triple Halide Bridges in Chiral (Mn2Mn6Na2I)-Mn-II-Na-III Cages: Structural and Magnetic Characterization
Author: Mayans Ayats, Júlia
Font Bardia, Ma. Mercedes
Escuer Fité, Albert
Keywords: Lligands
Propietats magnètiques
Metalls de transició
Magnetic properties
Transition metals
Issue Date: 5-Feb-2018
Publisher: American Chemical Society
Abstract: A family of decanuclear chiral clusters with a (Mn2Mn6Na2I)-Mn-II-Na-III core have been synthesized from enantiomerically pure Schiff bases. The new systems consist of two (Mn2Mn6Na2I)-Mn-II-Na-III units linked by rare triple chloro or bromo bridges between the divalent Mn cations. Susceptibility measurements point out the weak anti ferromagnetic interaction mediated by these kinds of bridges and afford the first magnetic measurements for the (mu-Br)(3) case.
Note: Versió postprint del document publicat a:
It is part of: Inorganic Chemistry, 2018, vol. 57, num. 3, p. 926-929
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ISSN: 0020-1669
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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