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http://hdl.handle.net/2445/163379
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DC Field | Value | Language |
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dc.contributor.author | Casanovas Bayo, Berta | - |
dc.contributor.author | Zinna, Francesco | - |
dc.contributor.author | Di Bari, Lorenzo | - |
dc.contributor.author | El Fallah El Boufrahi, Mohamed Salah | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.date.accessioned | 2020-05-31T09:23:12Z | - |
dc.date.available | 2020-05-31T09:23:12Z | - |
dc.date.issued | 2017-05-21 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/2445/163379 | - |
dc.description.abstract | The reaction of Ln(NO3)(2)center dot 6H(2)O (Ln = Tb and Eu) with (S)-(+)-2-phenylpropionic acid (S-HL) and 1,10-phenanthroline (phen) in EtOH/H2O allows the isolation of the dinuclear chiral compounds of the formula [Ln(2)(S-L)(6)(phen)(2)]center dot 2.5 center dot S-HL in which Ln = Tb (S-1), Ln = Eu (S-2). The same synthesis by using (R)-(-)-2-phenylpropionic acid (R-HL) instead of (S)-(+)-2-phenylpropionic acid allows the isolation of the enantiomeric compounds with the formula [Ln(2)(R-L)(6)(phen)(2)]center dot 2 center dot 5 center dot R-HL where Ln = Tb (R-1), Ln = Eu (R-2). All compounds show sensitized luminescence. The luminescence study, including the circularly polarized luminescence spectra of the four compounds, is reported. The magnetic behavior of S-1 and S-2 is also reported. | - |
dc.format.extent | 32 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/c6dt04686j | - |
dc.relation.ispartof | Dalton Transactions, 2017, vol. 46, num. 19, p. 6349-6357 | - |
dc.relation.uri | https://doi.org/10.1039/c6dt04686j | - |
dc.rights | (c) Casanovas Bayo, Berta et al., 2017 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.classification | Luminescència | - |
dc.subject.other | Layer structure (Solids) | - |
dc.subject.other | Luminescence | - |
dc.title | Circularly polarized luminescence on dinuclear Tb(III) and Eu(III) complexes with (S-) and (R-) 2-phenylpropionate | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 680372 | - |
dc.date.updated | 2020-05-31T09:23:12Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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680372.pdf | 2 MB | Adobe PDF | View/Open |
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