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Title: Solvent-controlled formation of monomeric and dimeric species containing Cu(II) acetate and 4-phenylpyridine
Author: Soldevila-Sanmartín, Joan
Ayllón, J. A.
Calvet Pallàs, Maria Teresa
Font Bardia, Ma. Mercedes
Pons, Josefina
Keywords: Coure
Estructura cristal·lina (Sòlids)
Layer structure (Solids)
Issue Date: 28-Jun-2017
Publisher: Elsevier Ltd
Abstract: Three copper(II) acetate complexes with 4-phenylpyridine (4-Phpy), namely [Cu(MeCO2)2(4- Phpy)2(H2O)2] (1), [Cu(MeCO2)2(4-Phpy)2(H2O)1.5] (2) and [Cu(MeCO2)2(4-Phpy)]2 (3), were synthesized and characterized by analytical and spectroscopic methods. Experimental conditions as solvent or temperature determine the species obtained. Crystal and molecular structure of 2 was determined by Xray diffraction. Compound 2 presents a singular structure, containing two crystallographic independent mononuclear units [Cu(MeCO2)2(4-Phpy)2(H2O)2] (2A) and [Cu(MeCO2)2(4-Phpy)2(H2O)] (2B) in its unit cell and each of these forms an independent 1-D chain through H-bonding.
Note: Versió postprint del document publicat a:
It is part of: Polyhedron, 2017, vol. 135, p. 36-40
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ISSN: 0277-5387
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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