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Title: Preparation, spectroscopic and structural study of copper(II) complexes derived from bulky pyridine ligands
Author: Guerrero, M.
Ayllón, J. A.
Calvet Pallàs, Maria Teresa
Bardia, Ma. Mercedes
Pons, J.
Keywords: Coure
Estructura cristal·lina (Sòlids)
Lligands (Bioquímica)
Layer structure (Solids)
Ligands (Biochemistry)
Issue Date: 8-Jun-2017
Publisher: Elsevier Ltd
Abstract: Three different binuclear tetracarboxylato-bridged copper(II) complexes supported by bulky pyridines ligands [Cu(m-MeCO2)2(dPy)]2 (dPy = 3-phenylpyridine (1), 2-benzylpyridine (2) and 4-acetylpyridine (3)) have been synthesised. These compounds were obtained from reaction of [Cu(MeCO2)2(H2O)]2 with pyridine-derived ligands in methanol at room temperature. All compounds were fully characterized by analytical and spectroscopic methods. The molecular structures were determined by X-ray diffraction analysis. All compounds consist of binuclear units where both Cu(II) atoms are linked by four syn-syn carboxylates bridges, showing a paddle-wheel unit, and exhibit interesting intermolecular interactions in the outer coordination sphere.
Note: Versió postprint del document publicat a:
It is part of: Polyhedron, 2017, vol. 134, p. 107-113
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ISSN: 0277-5387
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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