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http://hdl.handle.net/2445/163478| Title: | H-Bonded anion-anion complex trapped in a squaramido-based receptor |
| Author: | Prohens López, Rafael Portell Bueso, Anna Font Bardia, Ma. Mercedes Bauzá, Antonio Frontera, Antonio |
| Keywords: | Estructura cristal·lina (Sòlids) Anions Layer structure (Solids) Anions |
| Issue Date: | 12-Dec-2017 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | Herein we report the experimental observation (X-ray characterization) of an anion-anion complex (anion = hydrogen fumarate) stabilized by H-bonds that is trapped in a secondary squaramide receptor. High level ab initio calculations indicate that the anion- anion complex is thermodynamically unstable but kinetically stable with respect to the isolated anions |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c7cc09241e |
| It is part of: | Chemical Communications, 2017, vol. 54, num. 15, p. 1841-1844 |
| URI: | http://hdl.handle.net/2445/163478 |
| Related resource: | https://doi.org/10.1039/c7cc09241e |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 676857.pdf | 845.7 kB | Adobe PDF | View/Open |
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