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http://hdl.handle.net/2445/163711
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DC Field | Value | Language |
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dc.contributor.author | Escuer Fité, Albert | - |
dc.contributor.author | Cordero Crespo, Beatriz | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Teat, Simon J. | - |
dc.contributor.author | Roubeau, Olivier | - |
dc.date.accessioned | 2020-06-02T11:40:46Z | - |
dc.date.available | 2020-06-02T11:40:46Z | - |
dc.date.issued | 2016-01 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.uri | http://hdl.handle.net/2445/163711 | - |
dc.description.abstract | The systematic exploration of the reactivity of [Mn(hfacac)2] with R‐salicyloximes (R‐saloxH2: R = H, Me, Et) yielded a family of clusters with nuclearities ranging from Mn4 to Mn12. The compounds with formula [Mn6(O)2(salox)6(CF3COO)2(EtOH)4] (1 ) and [Mn12(salox)12(O)4(N3)4(H2O)2(MeOH)6] (4 ) show two or four linked {Mn(µ3‐O)(salox)3}+ triangular subunits. Magnetic measurements revealed spin ground states of S = 4 for 1 and S = 8 for 4 , as well as single‐molecule magnet responses and magnetic hysteresis above 2 K. The cubic [Mn4(Mesalox)4(MesaloxH)4] (2 ), the hexanuclear [Mn6(Etsalox)6(O)2(MeO)4(MeOH)2] (3 ) and the octanuclear [Mn8(Mesalox)6(O)2(N3)6(MeOH)8] (5 ) are polymorphs of previously reported systems. Small structural changes allows an S = 11 ground state for 3 . | - |
dc.format.extent | 43 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/ejic.201501372 | - |
dc.relation.ispartof | European Journal of Inorganic Chemistry, 2016, vol. 2016, num. 8, p. 1232-1241 | - |
dc.relation.uri | https://doi.org/10.1002/ejic.201501372 | - |
dc.rights | (c) Wiley-VCH, 2016 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Manganès | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.other | Manganese | - |
dc.subject.other | Magnetic properties | - |
dc.title | Manganese-salicyloximate clusters stating from [MnII(hfacac)2]: from Mn4 to Mn12 | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 662820 | - |
dc.date.updated | 2020-06-02T11:40:47Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
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662820.pdf | 1.66 MB | Adobe PDF | View/Open |
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