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http://hdl.handle.net/2445/164459
Title: | Coordination chemistry and catalysis with secondary phosphine oxides |
Author: | Gallen Ortiz, Albert Riera i Escalé, Antoni Verdaguer i Espaulella, Xavier Grabulosa, Arnald |
Keywords: | Compostos de coordinació Lligands Catàlisi Compostos fosforosos Coordination compounds Ligands Catalysis Phosphorus compounds |
Issue Date: | 21-Oct-2019 |
Publisher: | Royal Society of Chemistry |
Abstract: | Secondary phosphine oxides present a tautomeric equilibrium between the pentavalent oxide form (SPO) and the trivalent phosphinous acid (PA). This dichotomy is the origin of the rich coordination chemistry of this class of compounds. As the pentavalent oxide form usually predominates, SPOs are air-stable but at the same time metal coordination can shift the tautomerism towards the PA form, making the ligand act as an ordinary trivalent phosphine. For this reason this class of ligands have found application in numerous homogeneously catalysed reactions, including some enantioselective transformations. This review aims to give an up to date account on the synthesis, coordination chemistry and homogeneous catalysis with SPOs. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c9cy01501a |
It is part of: | Catalysis Science & Technology, 2019, vol. 9, num. 20, p. 5504-5561 |
URI: | http://hdl.handle.net/2445/164459 |
Related resource: | https://doi.org/10.1039/c9cy01501a |
ISSN: | 2044-4753 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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693369.pdf | 3.94 MB | Adobe PDF | View/Open |
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