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http://hdl.handle.net/2445/164597
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DC Field | Value | Language |
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dc.contributor.author | Fernandez-Valparis, Javier | - |
dc.contributor.author | Romo Fernández, Juan Manuel | - |
dc.contributor.author | Romea, Pedro | - |
dc.contributor.author | Urpí Tubella, Fèlix | - |
dc.contributor.author | Kowalski, Hubert | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2020-06-06T08:18:06Z | - |
dc.date.available | 2020-06-06T08:18:06Z | - |
dc.date.issued | 2015-07-02 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/2445/164597 | - |
dc.description.abstract | The structurally simple (Me3P)2NiCl2 complex catalyzes SN1-type alkylations of chiral N-acyl thiazolidinethiones with diarylmethyl methyl ethers and other stable carbenium cations. The former can contain a variety of functional groups and heteroatoms at the α-position. The resultant adducts are isolated as single diastereomers in high yields and can be converted into enantiomerically pure derivatives in a straightforward manner. | - |
dc.format.extent | 16 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.5b01626 | - |
dc.relation.ispartof | Organic Letters, 2015, vol. 17, num. 14, p. 3540-3543 | - |
dc.relation.uri | https://doi.org/10.1021/acs.orglett.5b01626 | - |
dc.rights | (c) American Chemical Society , 2015 | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Catàlisi asimètrica | - |
dc.subject.classification | Compostos de níquel | - |
dc.subject.classification | Alcohols | - |
dc.subject.classification | Èters | - |
dc.subject.other | Enantioselective catalysis | - |
dc.subject.other | Nickel compounds | - |
dc.subject.other | Alcohols | - |
dc.subject.other | Ethers | - |
dc.title | Stereoselective alkylation of (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones catalyzed by (Me3P)2NiCl2 | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 653265 | - |
dc.date.updated | 2020-06-06T08:18:06Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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653265.pdf | 1.95 MB | Adobe PDF | View/Open |
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