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http://hdl.handle.net/2445/165457| Title: | Dimerization of highly pyramidalized 3,4,8,9-tetramethyltetracyclo[4.4.0.03,9.04,8]dec-1(6)-ene to a hydrocarbon featuring four cyclohexane rings in boat conformation |
| Author: | Rey Carrizo, Matías Barniol-Xicota, Marta Font Bardia, Ma. Mercedes Vázquez Cruz, Santiago |
| Keywords: | Compostos policíclics Alquens Hidrocarburs Polycyclic compounds Alkenes Hydrocarbons |
| Issue Date: | 26-May-2014 |
| Publisher: | Wiley-VCH |
| Abstract: | The synthesis, chemical trapping, and dimerization of a highly pyramidalized alkene is reported. Its dimer is a unique nonacycle featuring three planar cyclobutane rings, four cyclopentane rings, and four cyclohexane rings in boat conformations. The X-ray diffraction analysis showed a H-H distance between the flagpole hydrogen atoms of 1.999 and a separation of 2.619 between the two flagpole carbon atoms. The three cyclobutane rings of the dimer were thermally stable |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1002/anie.201403985 |
| It is part of: | Angewandte Chemie-International Edition, 2014, vol. 53, num. 31, p. 8195-8199 |
| URI: | http://hdl.handle.net/2445/165457 |
| Related resource: | https://doi.org/10.1002/anie.201403985 |
| ISSN: | 1433-7851 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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|---|---|---|---|---|
| 641512.pdf | 763.79 kB | Adobe PDF | View/Open |
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