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Title: Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology
Author: Abbasi, Parisa
Athanasopoulou, Angeliki A.
Mazarakioti, Eleni C.
Gagnon, Kevin J.
Teat, Simon J.
Escuer Fité, Albert
Pilkington, Melanie
Stamatatos, Theocharis C.
Keywords: Ions
Issue Date: 21-Aug-2019
Publisher: Royal Society of Chemistry
Abstract: The synthesis of a new {Ni8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N3− ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials.
Note: Versió postprint del document publicat a:
It is part of: Dalton Transactions, 2019, vol. 48, num. 31, p. 11632-11636
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ISSN: 1477-9226
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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