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http://hdl.handle.net/2445/172412
Title: | Click chemistry as a route to the synthesis of structurally new and magnetically interesting coordination clusters: a {NiII8} complex with a trapezoidal prismatic topology |
Author: | Abbasi, Parisa Athanasopoulou, Angeliki A. Mazarakioti, Eleni C. Gagnon, Kevin J. Teat, Simon J. Escuer Fité, Albert Pilkington, Melanie Stamatatos, Theocharis C. |
Keywords: | Ions Molècules Ions Molecules |
Issue Date: | 21-Aug-2019 |
Publisher: | Royal Society of Chemistry |
Abstract: | The synthesis of a new {Ni8} cluster bearing tetrazolate- and azido-bridging ligands, and supported by chelating α-methyl-2-pyridine-methanol (mpmH) groups, is described herein. The reported compound has a unique trapezoidal prismatic topology, resulting from an unexpected in situ click reaction between the MeCN reaction solvent and the N3− ions under mild, room-temperature conditions. Such a click chemistry approach to the preparation of 0-D compounds is relatively unexplored and represents a fruitful strategy for the synthesis of new coordination clusters and molecule-based magnetic materials. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1039/c9dt01998g |
It is part of: | Dalton Transactions, 2019, vol. 48, num. 31, p. 11632-11636 |
URI: | http://hdl.handle.net/2445/172412 |
Related resource: | https://doi.org/10.1039/c9dt01998g |
ISSN: | 1477-9226 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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