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http://hdl.handle.net/2445/172836
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DC Field | Value | Language |
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dc.contributor.author | Pinto Martínez, Andrea | - |
dc.contributor.author | Spigolon, G. | - |
dc.contributor.author | Gavara, Raquel | - |
dc.contributor.author | Zonta, C. | - |
dc.contributor.author | Licini, G. | - |
dc.contributor.author | Rodríguez Raurell, Laura | - |
dc.date.accessioned | 2020-12-17T11:56:13Z | - |
dc.date.available | 2021-07-21T05:10:26Z | - |
dc.date.issued | 2020-07-21 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/2445/172836 | - |
dc.description.abstract | Three gold(I) tripodal complexes containing the tris(2-pyridylmethyl)amine (TPA) ligand coordinated to Au-PR3 moieties (PR3 = 1,3,5-triaza-7-phosphatricyclo[3.3.1.13.7]decane, PTA (1), 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, DAPTA (2) and triphenylphosphane (3)) were prepared together with a cage-like structure containing triphosphane 1,1,1-tris(diphenylphosphinomethyl)ethane (4). The luminescence of these complexes has been studied and they show a red shift upon the formation of heterometallic complexes by reaction with Zn(NO3)2, CuCl and [Cu(CH3CN)4]BF4. The different coordination motifs of the Zn2+ and Cu+ heterometallic species and the resulting changes in the recorded absorption, emission and NMR spectra were analysed and supported by TD-DFT calculations. | - |
dc.format.extent | 13 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/d0dt02564j | - |
dc.relation.ispartof | Dalton Transactions, 2020, vol. 49, p. 14613-14625 | - |
dc.relation.uri | https://doi.org/10.1039/d0dt02564j | - |
dc.rights | (c) Pinto, Andrea et al., 2020 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Or | - |
dc.subject.classification | Luminescència | - |
dc.subject.classification | Optoelectrònica | - |
dc.subject.other | Gold | - |
dc.subject.other | Luminescence | - |
dc.subject.other | Optoelectronics | - |
dc.title | Tripodal gold(I) polypyridyl complexes and their Cu+ and Zn2+ heterometallic derivatives. Effects on luminescence | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 705351 | - |
dc.date.updated | 2020-12-17T11:56:13Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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705351.pdf | 3.49 MB | Adobe PDF | View/Open |
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