Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/173441
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DC Field | Value | Language |
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dc.contributor.author | Saladrigas, Mar | - |
dc.contributor.author | Puig Bosch, Jordi | - |
dc.contributor.author | Bonjoch i Sesé, Josep | - |
dc.contributor.author | Bradshaw, Ben | - |
dc.date.accessioned | 2021-01-28T08:58:53Z | - |
dc.date.available | 2021-10-05T05:10:13Z | - |
dc.date.issued | 2020-10-05 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | http://hdl.handle.net/2445/173441 | - |
dc.description.abstract | The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes, employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes as viable acceptor groups in MHAT reactions. The insights gained in this study led to the reexamination of the previously reported intramolecular version of the reaction, and the addition of FeII salts allowed the development of a more efficient second-generation approach. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.0c03081 | - |
dc.relation.ispartof | Organic Letters, 2020, vol. 22, p. 8111-8115 | - |
dc.relation.uri | https://doi.org/10.1021/acs.orglett.0c03081 | - |
dc.rights | (c) American Chemical Society , 2020 | - |
dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | - |
dc.subject.classification | Alquens | - |
dc.subject.classification | Catàlisi | - |
dc.subject.classification | Enllaços químics | - |
dc.subject.classification | Química orgànica | - |
dc.subject.other | Alkenes | - |
dc.subject.other | Catalysis | - |
dc.subject.other | Chemical bonds | - |
dc.subject.other | Organic chemistry | - |
dc.title | Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 705813 | - |
dc.date.updated | 2021-01-28T08:58:54Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
Files in This Item:
File | Description | Size | Format | |
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705813.pdf | 781.59 kB | Adobe PDF | View/Open |
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