1. Dipòsit Digital de la Universitat de Barcelona
  2. Recerca
  3. Química Inorgànica i Orgànica
  4. Articles publicats en revistes (Química Inorgànica i Orgànica)
Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/175936
Full metadata record
DC FieldValueLanguage
dc.contributor.authorTarushi, Alketa-
dc.contributor.authorHatzidimitriou, Antonios G.-
dc.contributor.authorEstrader i Bofarull, Marta-
dc.contributor.authorKessissoglou, Dimitris P.-
dc.contributor.authorTangoulis, Vassilis-
dc.contributor.authorPsomas, George-
dc.date.accessioned2021-03-31T15:23:28Z-
dc.date.available2021-03-31T15:23:28Z-
dc.date.issued2017-06-07-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/2445/175936-
dc.description.abstractThe interaction of Mn(ClO4)2·6H2O with salicylaldoxime (H2sao) in the presence of nonsteroidal anti-inflammatory drug (NSAID) sodium diclofenac (Nadicl) or indomethacin (Hindo) leads to the formation of the hexanuclear Mn(III) clusters [Mn6(O)2(dicl)2(sao)6(CH3OH)6] (1) and [Mn6(O)2(indo)2(sao)6(H2O)4] (2) both characterized as stepladder inverse-9-metallacrown-3 accommodating dicl- or indo- ligands, respectively. When the interaction of MnCl2·4H2O with Nadicl or Hindo is in the absence of H2sao, the mononuclear Mn(II) complexes [Mn(dicl)2(CH3OH)4] (3) and [Mn(indo)2(CH3OH)4] (4) were isolated. The complexes were characterized by physicochemical and spectroscopic techniques, and the structure of complexes 1 and 2 was characterized by X-ray crystallography. Magnetic measurements (dc and ac) were carried out in order to investigate the nature of magnetic interactions between the magnetic ions and the overall magnetic behavior of the complexes.-
dc.format.extent10 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b00655-
dc.relation.ispartofInorganic Chemistry, 2017, vol. 56, num. 12, p. 7048-7057-
dc.relation.urihttps://doi.org/10.1021/acs.inorgchem.7b00655-
dc.rights(c) American Chemical Society , 2017-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationManganès-
dc.subject.classificationAgents antiinflamatoris-
dc.subject.classificationCompostos complexos-
dc.subject.otherManganese-
dc.subject.otherAntiinflammatory agents-
dc.subject.otherComplex compounds-
dc.titleToward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec675371-
dc.date.updated2021-03-31T15:23:28Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

Files in This Item:
File Description SizeFormat 
675371.pdf1.27 MBAdobe PDFView/Open
Show simple item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.