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http://hdl.handle.net/2445/180468| Title: | NOx Storage on BaTi0.8Cu0.2O3 Perovskite Catalysts: Addressing a Feasible Mechanism |
| Author: | Albaladejo-Fuentes, Vicente Sánchez Adsuar, María Salvadora Anderson, James A. Illán Gómez, María José |
| Keywords: | Nitrits Nitrats Catàlisi Nitrites Nitrates Catalysis |
| Issue Date: | 21-Aug-2021 |
| Publisher: | MDPI |
| Abstract: | The NOx storage mechanism on BaTi0.8Cu0.2O3 catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage-regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba2TiO4 plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O2 and NO/N2 show that nitrites and nitrates are formed on the perovskite during the NOx storage process. Thus, it seems that, as for model NSR catalysts, the NOx storage on BaTi0.8Cu0.2O3 catalyst takes place by both "nitrite" and "nitrate" routes, with the main pathway being highly dependent on the temperature and the time on stream: (i) at T < 350 °C, NO adsorption leads to nitrites formation on the catalyst and (ii) at T > 350 °C, the catalyst activity for NO oxidation promotes NO2 generation and the nitrate formation. |
| Note: | Reproducció del document publicat a: https://doi.org/10.3390/nano11082133 |
| It is part of: | Nanomaterials, 2021, vol. 11, num. 8, p. 2133 |
| URI: | http://hdl.handle.net/2445/180468 |
| Related resource: | https://doi.org/10.3390/nano11082133 |
| ISSN: | 2079-4991 |
| Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
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