1. Dipòsit Digital de la Universitat de Barcelona
  2. Recerca
  3. Química Inorgànica i Orgànica
  4. Articles publicats en revistes (Química Inorgànica i Orgànica)
Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/181251
Full metadata record
DC FieldValueLanguage
dc.contributor.authorRosental, Marian-
dc.contributor.authorColdman, Richard N.-
dc.contributor.authorMoro, Artur J.-
dc.contributor.authorAngurell Purroy, Inmaculada-
dc.contributor.authorGomila, Rosa M.-
dc.contributor.authorFrontera, Antonio-
dc.contributor.authorLima, João Carlos-
dc.contributor.authorRodríguez Raurell, Laura-
dc.date.accessioned2021-11-17T13:03:09Z-
dc.date.available2021-11-17T13:03:09Z-
dc.date.issued2021-04-22-
dc.identifier.issn1420-3049-
dc.identifier.urihttp://hdl.handle.net/2445/181251-
dc.description.abstractThe synthesis of two new phosphane-gold(I)-napthalimide complexes has been performed and characterized. The compounds present luminescent properties with denoted room temperature phosphorescence (RTP) induced by the proximity of the gold(I) heavy atom that favors intersystem crossing and triplet state population. The emissive properties of the compounds together with the planarity of their chromophore were used to investigate their potential as hosts in the molecular recognition of different polycyclic aromatic hydrocarbons (PAHs). Naphthalene, anthracene, phenanthrene, and pyrene were chosen to evaluate how the size and electronic properties can affect the host:guest interactions. Stronger affinity has been detected through emission titrations for the PAHs with extended aromaticity (anthracene and pyrene) and the results have been supported by DFT calculation studies.-
dc.format.extent14 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherMDPI-
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.3390/molecules26092444-
dc.relation.ispartofMolecules, 2021, vol. 26, num. 9, p. 2444-2457-
dc.relation.urihttps://doi.org/10.3390/molecules26092444-
dc.rightscc-by (c) Rosental, Marian et al., 2021-
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationOr-
dc.subject.classificationFosforescència-
dc.subject.classificationHidrocarburs aromàtics policíclics-
dc.subject.otherGold-
dc.subject.otherPhosphorescence-
dc.subject.otherPolycyclic aromatic hydrocarbons-
dc.titleUsing room temperature Phosphorescence of Gold(I) complexes for PAHs sensing-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec713108-
dc.date.updated2021-11-17T13:03:09Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid33922155-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Nanociència i Nanotecnologia (IN2UB))

Files in This Item:
File Description SizeFormat 
713108.pdf3.75 MBAdobe PDFView/Open
Show simple item record


This item is licensed under a Creative Commons License Creative Commons