Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/183586
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sánchez-Férez, Francisco | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2022-02-28T12:36:51Z | - |
dc.date.available | 2023-07-05T05:10:19Z | - |
dc.date.issued | 2021-07-05 | - |
dc.identifier.issn | 0022-2860 | - |
dc.identifier.uri | http://hdl.handle.net/2445/183586 | - |
dc.description.abstract | Extensively research has been devoted to the isolation and characterization of Cu(II) coordination polymers. Since many aspects can influence the final crystal structure, the effect of the solvent molecules through intermolecular interactions has been proven to be a determining factor. Herein, we elucidated the structure of two Cu(II) concomitant 1D polymers containing piperonylic acid (HPip) and 4,4 -bipyridine (4,4-bipy), which were simultaneously crystallized and subsequently isolated changing the synthetic conditions. Complex {[Cu(Pip)2(4,4-bipy)]}n (1) exhibits zig-zag polymeric chains while {[Cu(Pip)2(4,4 -bipy)(H2O)]¿ 1/2(4,4-bipy)¿(DMF)}n (2) displays linear polymeric chains stacked by water¿¿¿carboxylate intermolecular interactions, forming voids occupied by alternated guest 4,4-bipy and DMF molecules. | - |
dc.format.extent | 27 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2021.130219 | - |
dc.relation.ispartof | Journal of Molecular Structure, 2021, vol. 1235, num. 130219 | - |
dc.relation.uri | https://doi.org/10.1016/j.molstruc.2021.130219 | - |
dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2021 | - |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Radiocristal·lografia | - |
dc.subject.classification | Compostos organometàl·lics | - |
dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
dc.subject.other | X-ray crystallography | - |
dc.subject.other | Organometallic compounds | - |
dc.subject.other | Layer structure (Solids) | - |
dc.title | Cu(II) coordination polymers with 4,4 '-bipyridine. Synthesis and crystal structures | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 718755 | - |
dc.date.updated | 2022-02-28T12:36:52Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
718755.pdf | 1.41 MB | Adobe PDF | View/Open |
This item is licensed under a
Creative Commons License