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DC Field | Value | Language |
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dc.contributor.author | Jana, Srikanta | - |
dc.contributor.author | Karim, Suhana | - |
dc.contributor.author | Paul, Sukanya | - |
dc.contributor.author | Zangrando, Ennio | - |
dc.contributor.author | Salah El Fallah, Mohamed | - |
dc.contributor.author | Das, Debasis | - |
dc.contributor.author | Sinha, Chittaranjan | - |
dc.date.accessioned | 2022-03-24T18:18:01Z | - |
dc.date.available | 2022-03-24T18:18:01Z | - |
dc.date.issued | 2021-12-05 | - |
dc.identifier.issn | 0022-2860 | - |
dc.identifier.uri | http://hdl.handle.net/2445/184369 | - |
dc.description.abstract | The 1D coordination polymer, [Cu 2 ( μ2 -OH) 2 (DABA) 2 ] n ( 1 ), (HDABA = 4-Diallylamino-benzoic acid) is characterized by Single crystal X-Ray diffraction analysis. The structure switches to a 2D geometry by hy- drogen bonding interactions. Hand grinding aqueous suspension of the coordination polymer, 1 , present in nano regime of av . 100 nm dimension and shows catalytic performance in the reduction of toxic nitro- phenols to corresponding aminophenols by NaBH 4 . The rate constant values ( κapp ) are 2.4 ×10 −3 (4-NP), 5.3 ×10 −3 (2,4-DNP) and 5.6 ×10 −3 (2,4,6-TNP) s −1 are much higher than reduction by only NaBH 4 . The susceptibility measurements ( χM T ) of Cu(II) coordination polymer indicates the presence of a very weak antiferromagnetic coupling between the metal centres. The hand grinding technique and reusability of 1 makes the approach chemically green, cost effective and attracts the attention towards the real-life application. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier B.V. | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1016/j.molstruc.2021.131058 | - |
dc.relation.ispartof | Journal of Molecular Structure, 2021, vol. 1245, p. 131058 | - |
dc.relation.uri | https://doi.org/10.1016/j.molstruc.2021.131058 | - |
dc.rights | cc-by-nc-nd (c) Jana, Srikanta, et al., 2021 | - |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Polímers | - |
dc.subject.classification | Magnetoquímica | - |
dc.subject.other | Polymers | - |
dc.subject.other | Magnetochemistry | - |
dc.title | Carboxylato bridging Cu(II) coordination polymer: Structure, magnetism and catalytic reduction of nitrophenols | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 719252 | - |
dc.date.updated | 2022-03-24T18:18:01Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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