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http://hdl.handle.net/2445/185088
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DC Field | Value | Language |
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dc.contributor.author | Tubau Ribot, Ànnia | - |
dc.contributor.author | Rodríguez Raurell, Laura | - |
dc.contributor.author | Lázaro, Ariadna | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2022-04-22T14:24:57Z | - |
dc.date.available | 2022-12-31T06:10:28Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 1144-0546 | - |
dc.identifier.uri | http://hdl.handle.net/2445/185088 | - |
dc.description.abstract | The reaction of Ln(NO3)2·6H2O salts (Ln = Eu and Tb) with an excess of 2-fluorobenzoic acid (H-2FBz) in an ethanol/water mixture allows the isolation of dinuclear compounds with the formula [Ln2(μ2-2FBz)4(2FBz)2(H-2FBz)2(H2O)2] (Ln = Eu (1) and Tb (2), 2FBz = 2-fluorobenzoate). A solid-state photoluminescence study of complexes 1 and 2 shows the 4f-4f lanthanide transitions in the visible range with improved emission quantum yields. 1 and 2 are water soluble and photoluminescence studies have also been performed in water and D2O solutions, showing that the emission due to the 4f-4f electronic transitions is still present. The magnetic behaviors of 1 and 2 are also reported. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1039/d1nj04335h | - |
dc.relation.ispartof | New Journal of Chemistry, 2021, vol. 45, p. 22208 | - |
dc.relation.uri | https://doi.org/10.1039/d1nj04335h | - |
dc.rights | (c) Tubau Ribot, Ànnia et al., 2021 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Luminescència | - |
dc.subject.classification | Terbi | - |
dc.subject.other | Luminescence | - |
dc.subject.other | Terbium | - |
dc.title | Improving the emission quantum yield in dinuclear Eu(III) and Tb(III) complexes with 2-fluorobenzoate. | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 718061 | - |
dc.date.updated | 2022-04-22T14:24:57Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Nanociència i Nanotecnologia (IN2UB)) |
Files in This Item:
File | Description | Size | Format | |
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718061.pdf | 912.24 kB | Adobe PDF | View/Open |
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