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http://hdl.handle.net/2445/185127
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DC Field | Value | Language |
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dc.contributor.author | Calvo Galve, Néstor | - |
dc.contributor.author | Abrishamkar, Afshin | - |
dc.contributor.author | Sorrenti, Alessandro | - |
dc.contributor.author | Di Rienzo, Lorenzo | - |
dc.contributor.author | Satta, Mauro | - |
dc.contributor.author | D'Abramo, Marco | - |
dc.contributor.author | Coronado, Eugenio | - |
dc.contributor.author | De Mello, Andrew J. | - |
dc.contributor.author | Mínguez Espallargas, Guillem | - |
dc.contributor.author | Puigmartí-Luis, Josep | - |
dc.date.accessioned | 2022-04-26T15:05:39Z | - |
dc.date.available | 2022-04-26T15:05:39Z | - |
dc.date.issued | 2021-07-12 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2445/185127 | - |
dc.description.abstract | Coordinationpolymers(CPs),includingmetal-organicframeworks(MOFs),are crystallinematerialswithpromisingapplicationsin electronics,magnetism,catalysis,andgas storage/separation.However,the mechanismsandpath-waysunderlyingtheirformationremainlargelyundisclosed.Herein,we demonstratethatdiffusion-controlledmixingofreagentsat the veryearlystagesof the crystallizationprocess(i.e., within 40 ms),achievedby usingcontinuous-flowmicrofluidicdevices,can be usedto enablenovelcrystallizationpathwaysofaprototypicalspin-crossover MOFtowards itsthermodynamicproduct.In particular,twodistinctandunprecedentednucleation-growth pathwayswere experimen-tallyobservedwhencrystallizationwas triggeredundermicro-fluidicmixing.Full-atommoleculardynamicssimulationsalsoconfirmthe occurrenceof thesetwo distinctpathwaysduringcrystalgrowth.In sharpcontrast,acrystallizationby particleattachmentwas observedunderbulk(turbulent)mixing.Theseunprecedentedresultsprovideasoundbasisfor understandingthe growth of CPsand openup newavenuesfor the engineer-ing of porousmaterialsby usingout-of-equilibriumconditions | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1002/anie.202101611 | - |
dc.relation.ispartof | Angewandte Chemie-International Edition, 2021, vol. 60, num. 29, p. 15920-15927 | - |
dc.relation.uri | https://doi.org/10.1002/anie.202101611 | - |
dc.rights | cc-by-nc (c) Calvo Galve, Néstor, et al., 2021 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/es/ | * |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Polímers | - |
dc.subject.classification | Cristal·lització | - |
dc.subject.classification | Microfluídica | - |
dc.subject.other | Polymers | - |
dc.subject.other | Crystallization | - |
dc.subject.other | Microfluidics | - |
dc.title | Exploiting Reaction-Diffusion Conditions to Trigger Pathway Complexity in the Growth of a MOF | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 719750 | - |
dc.date.updated | 2022-04-26T15:05:39Z | - |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/677020/EU//microCrysFact | - |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/724681/EU//S-CAGE | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB)) Publicacions de projectes de recerca finançats per la UE |
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File | Description | Size | Format | |
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719750.pdf | 1.92 MB | Adobe PDF | View/Open |
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