Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/185131
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Abad Galán, Laura | - |
dc.contributor.author | Aguilà Avilés, David | - |
dc.contributor.author | Guyot, Yannick | - |
dc.contributor.author | Velasco Amigó, Verónica | - |
dc.contributor.author | Roubeau, Olivier | - |
dc.contributor.author | Teat, Simon J. | - |
dc.contributor.author | Massi, Massimiliano | - |
dc.contributor.author | Aromí Bedmar, Guillem | - |
dc.date.accessioned | 2022-04-26T17:39:52Z | - |
dc.date.available | 2022-04-26T17:39:52Z | - |
dc.date.issued | 2021-01-15 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/2445/185131 | - |
dc.description.abstract | The ligand H3 L (6-[3-oxo-3-(2-hydroxyphenyl)propionyl]pyridine-2-carboxylic acid), which exhibits two different coordination pockets, has been exploited to engender and study energy transfer (ET) in two dinuclear [LnIII LnIII '] analogues of interest, [EuYb] and [NdYb]. Their structural and physical properties have been compared with newly synthesised analogues featuring no possible ET ([EuLu], [NdLu], and [GdYb]) and with the corresponding homometallic [EuEu] and [NdNd] analogues, which have been previously reported. Photophysical data suggest that ET between EuIII and YbIII does not occur to a significant extent, whereas emission from YbIII originates from sensitisation of the ligand. In contrast, energy migration seems to be occurring between the two NdIII centres in [NdNd], as well as in [NdYb], in which YbIII luminescence is thus, in part, sensitised by ET from Nd. This study shows the versatility of this molecular platform to further the investigation of lanthanide-to-lanthanide ET phenomena in defined molecular systems. | - |
dc.format.extent | 12 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/chem.202005327 | - |
dc.relation.ispartof | Chemistry-A European Journal, 2021, vol. 27, num. 25, p. 7288-7299 | - |
dc.relation.uri | https://doi.org/10.1002/chem.202005327 | - |
dc.rights | (c) Wiley-VCH, 2021 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Sistemes complexos | - |
dc.subject.classification | Transferència d'energia | - |
dc.subject.other | Complex systems | - |
dc.subject.other | Energy transfer | - |
dc.title | Accessing Lanthanide-to-Lanthanide Energy Transfer in a Family of Site-Resolved [LnIIILnIII'] Heterometallic Complexes | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 715303 | - |
dc.date.updated | 2022-04-26T17:39:52Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Institut de Nanociència i Nanotecnologia (IN2UB)) Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
715303.pdf | 1.57 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.