Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/189775
Full metadata record
DC FieldValueLanguage
dc.contributor.authorRojo, Pep-
dc.contributor.authorRiera i Escalé, Antoni-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.date.accessioned2022-10-10T18:16:59Z-
dc.date.available2022-10-10T18:16:59Z-
dc.date.issued2021-06-03-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/2445/189775-
dc.description.abstractBOM-tert-butylmethylphosphinite borane is an efficient electrophilic P-stereogenic transfer reagent for the synthesis of bulky tertiary phosphines. The novel methodology relies on a one-pot deprotection/substitution process. The substitution of the trivalent phosphinite takes place with high stereospecificity and provides the products with inversion of configuration at the phosphorus atom. The potential of the methodology is demonstrated with the synthesis of a wide scope of tertiary phoshines in excellent enantiomeric excess. Finally the methodology was applied to the synthesis of bulky P-stereogenic BisP* ligand analog.-
dc.format.extent5 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.1c01522-
dc.relation.ispartofOrganic Letters, 2021, vol. 23, num. 12, p. 4802-4806-
dc.relation.urihttps://doi.org/10.1021/acs.orglett.1c01522-
dc.rights(c) American Chemical Society , 2021-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationFòsfor-
dc.subject.classificationLligands-
dc.subject.classificationQuímica analítica-
dc.subject.otherPhosphorus-
dc.subject.otherLigands-
dc.subject.otherAnalytical chemistry-
dc.titleBOM-phosphinite as an electrophilic P-stereogenic transfer reagent for the synthesis of bulky phosphines. Synthesis of tert-butyl(3,5-di-tert-butylphenyl)BisP*-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec723084-
dc.date.updated2022-10-10T18:16:59Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))
Articles publicats en revistes (Química Inorgànica i Orgànica)

Files in This Item:
File Description SizeFormat 
723084.pdf2.55 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.