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DC Field | Value | Language |
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dc.contributor.author | Mautner, Franz A. | - |
dc.contributor.author | Bierbaumer, Florian | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.contributor.author | Speed Castro, Saskia | - |
dc.contributor.author | Tubau Ribot, Ànnia | - |
dc.contributor.author | Fischer, Roland C. | - |
dc.contributor.author | Massoud, Salah S. | - |
dc.date.accessioned | 2023-01-10T17:56:56Z | - |
dc.date.available | 2023-01-10T17:56:56Z | - |
dc.date.issued | 2022 | - |
dc.identifier.issn | 2312-7481 | - |
dc.identifier.uri | http://hdl.handle.net/2445/192045 | - |
dc.description.abstract | A novel series of polypyridyl adducts, [Sm(ntfa)3(NN)] (2-4), with ntfa = 4,4,4-trifluoro-1-(naphthalen-2-yl)-1,3-butanedionate, NN = 2,2′-bipyridine (bipy), 4,4′-dimethyl-2,2′-bipyridine (4,4′-Me2bipy), and 5,5′-dimethyl-2,2′-bipyridine (5,5′-Me2bipy) were synthesized from the precursor complex [Sm(ntfa)3(MeOH)2] (1) and the corresponding pyridyl ligands. Single X-ray crystallography showed that the complexes displayed 8-coordinated geometry. The solid pyridyl adducts 2-4 exhibited emission of luminescence in the NIR and visible regions with close quantum yields (QY = 0.20-0.25%). The magnetic data of 1-4 showed larger values than those expected for magnetically noncoupled Sm(III) complexes in the 6H5/2 ground state, with no saturation on the applied high magnetic field static at a temperature of 2 K. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/magnetochemistry8070072 | - |
dc.relation.ispartof | Magnetochemistry, 2022, vol. 8, p. 72 | - |
dc.relation.uri | https://doi.org/10.3390/magnetochemistry8070072 | - |
dc.rights | cc-by (c) Mautner, Franz A. et al., 2022 | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Luminescència | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.classification | Raigs X | - |
dc.subject.other | Luminescence | - |
dc.subject.other | Magnetic properties | - |
dc.subject.other | X-rays | - |
dc.title | Magnetic and Luminescence Properties of 8-Coordinated Pyridyl Adducts of Samarium(III) Complexes Containing 4,4,4-Trifluoro-1-(naphthalen-2-yl)-1,3-butanedionate | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 724729 | - |
dc.date.updated | 2023-01-10T17:56:56Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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724729.pdf | 1.58 MB | Adobe PDF | View/Open |
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