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https://hdl.handle.net/2445/195038| Title: | Synthesis and study of the luminescent properties of gold(I) organometallic complexes |
| Other Titles: | Síntesi i estudi de les propietats luminescents de complexos organometal·lics d’or(I) |
| Author: | Sevillano Santamaria, Alba |
| Director/Tutor: | Angurell Purroy, Inmaculada |
| Keywords: | Cromòfor Alquinil Luminescència Treballs de fi de grau Chromophore Alkynyl Luminescence Bachelor's theses |
| Issue Date: | Jan-2023 |
| Abstract: | The study of gold-(I) organometallic complexes has been of great interest over the last few years due to their luminescent properties. These compounds have a wide range of applications in different research fields such as chemosensors, photodynamic therapy and optical limiting. In this project, several mono- and dinuclear gold-(I) complexes have been synthesized. These linear complexes contain a triphenylene ligand with alkynyl moieties at the first coordination position of gold atom and a phosphane at the second coordination position. Several monophosphanes (-PTA, -PPh3, -PMe3) and diphosphanes (-dppe, -dppm, -xantphos and -spanphos) have been used to obtain gold complexes with different properties. 1H NMR, 31P-{H} NMR, IR, ESI-MS(+) techniques have been used to characterize the products and confirm the successful formation of gold-(I) derivatives. Lastly, the luminescent properties of the gold-(I) complexes have been studied recording the absorption and emission spectra |
| Note: | Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2023, Tutora: Inmaculada Angurell Purroy |
| URI: | https://hdl.handle.net/2445/195038 |
| Appears in Collections: | Treballs Finals de Grau (TFG) - Química |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| TFG_QU Sevillano Santamaria, Alba.pdf | 1.96 MB | Adobe PDF | View/Open Request a copy |
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