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http://hdl.handle.net/2445/195928
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DC Field | Value | Language |
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dc.contributor.author | Mautner, Franz A. | - |
dc.contributor.author | Bierbaumer, Florian | - |
dc.contributor.author | Fischer, Roland C. | - |
dc.contributor.author | Tubau Ribot, Ànnia | - |
dc.contributor.author | Speed Castro, Saskia | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.contributor.author | Massoud, Salah S. | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.contributor.author | Gómez Coca, Silvia | - |
dc.date.accessioned | 2023-03-24T14:57:40Z | - |
dc.date.available | 2023-03-24T14:57:40Z | - |
dc.date.issued | 2022 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/2445/195928 | - |
dc.description.abstract | Four novel CeIII mononuclear complexes of formulas [Ce(ntfa)3(MeOH)2] (1), [Ce(ntfa)3(5,5′-Me2bipy)] (2), [Ce(ntfa)3(terpy)] (3), and [Ce(ntfa)3(bipy)2] (4), where ntfa = 4,4,4-trifluoro-1-(naphthalen-2-yl)butane-1,3-dionato, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-dipyridyl, terpy = 2,2′:6′,2″-terpyridine, and bipy = 2,2′-bipyridine, have been synthesized and structurally characterized with CeIII displaying coordination numbers of 8, 8, 9, and 10, respectively. Magnetic measurements indicate that all the complexes show a field-induced single-ion magnet behavior under a small applied dc field. The magnetic analysis shows the relevance of the different spin relaxation mechanisms in the magnetic relaxation of the CeIII compounds, with special emphasis on the local-mode process. Multiconfigurational calculations were also performed to get more information on the axiality of the compounds. | - |
dc.format.extent | 13 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1021/acs.inorgchem.2c00958 | - |
dc.relation.ispartof | Inorganic Chemistry, 2022, vol. 61, num. 29, p. 11124-11136 | - |
dc.relation.uri | https://doi.org/10.1021/acs.inorgchem.2c00958 | - |
dc.rights | cc-by (c) Mautner, Franz A. et el., 2022 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Propietats magnètiques | - |
dc.subject.classification | Ions | - |
dc.subject.classification | Lligands | - |
dc.subject.other | Magnetic properties | - |
dc.subject.other | Ions | - |
dc.subject.other | Ligands | - |
dc.title | Insights into the Spin Dynamics of Mononuclear Cerium(III) Single-Molecule Magnets | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 724730 | - |
dc.date.updated | 2023-03-24T14:57:40Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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File | Description | Size | Format | |
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724730.pdf | 5.46 MB | Adobe PDF | View/Open |
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