A new method based on selective fluorescent polymers (PSresin) for the analysis of ⁹⁰Sr in presence of ²¹⁰Pb in environmental samples

Abstract

90Sr is of major concern in emergency and environmental control plans. It is one of the main fission products in nuclear facilities and is a high-energy beta emitter that presents chemical properties similar to those of calcium. 90Sr is commonly detected using methods based on liquid scintillation counting (LSC) following a chemical separation to remove potential interferences. However, these methods generate mixed wastes (hazardous and radioactive). In recent years, an alternative strategy using PSresins has been developed. For 90Sr analysis with PSresins, 210Pb is the main interferent that should be considered, as it is also strongly retained in the PSresin. In this study, a procedure was developed involving a precipitation with iodates to separate lead from strontium before the PSresin separation. Moreover, the method developed was compared with well-established and routinely used methods based on LSC, revealing that the new method produced equivalent results in less time and with less waste generation.