Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/208268
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Biosca, Maria | - |
dc.contributor.author | Cruz Sánchez, Pol de la | - |
dc.contributor.author | Faiges, Jorge | - |
dc.contributor.author | Margalef, Jèssica | - |
dc.contributor.author | Salomó i Prat, Ernest | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.contributor.author | Ferré, Joan | - |
dc.contributor.author | Maseras, Feliu | - |
dc.contributor.author | Besora, Maria | - |
dc.contributor.author | Pàmies, Oscar | - |
dc.contributor.author | Diéguez, Montserrat | - |
dc.date.accessioned | 2024-03-01T17:52:01Z | - |
dc.date.available | 2024-03-01T17:52:01Z | - |
dc.date.issued | 2023-02-14 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | http://hdl.handle.net/2445/208268 | - |
dc.description.abstract | The Ir-MaxPHOX-type catalysts demonstrated high catalytic performance in the hydrogenation of a wide range of nonchelating olefins with different geometries, substitution patterns, and degrees of functionalization. These air-stable and readily available catalysts have been successfully applied in the asymmetric hydrogenation of di-, tri-, and tetrasubstituted olefins (ee′s up to 99%). The combination of theoretical calculations and deuterium labeling experiments led to the uncovering of the factors responsible for the enantioselectivity observed in the reaction, allowing the rationalization of the most suitable substrates for these Ir-catalysts. | - |
dc.format.extent | 16 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1021/acscatal.2c05579 | - |
dc.relation.ispartof | ACS Catalysis, 2023, vol. 13, p. 3020-3035 | - |
dc.relation.uri | https://doi.org/10.1021/acscatal.2c05579 | - |
dc.rights | cc-by (c) Biosca, Maria et al., 2023 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Hidrogenació | - |
dc.subject.classification | Catalitzadors | - |
dc.subject.classification | Hidrocarburs | - |
dc.subject.other | Hydrogenation | - |
dc.subject.other | Catalysts | - |
dc.subject.other | Hydrocarbons | - |
dc.title | P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 739470 | - |
dc.date.updated | 2024-03-01T17:52:01Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
832350.pdf | 4.6 MB | Adobe PDF | View/Open |
This item is licensed under a
Creative Commons License