Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/210180
Title: | Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime |
Author: | Vlahopoulou, Gina Escuer Fité, Albert Font Bardia, Ma. Mercedes Calvet Pallàs, Maria Teresa |
Keywords: | Química inorgànica Estructura cristal·lina (Sòlids) Inorganic chemistry Layer structure (Solids) |
Issue Date: | 2012 |
Publisher: | Elsevier B.V. |
Abstract: | The use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2011.11.037 |
It is part of: | Inorganic Chemistry Communications, 2012, vol. 16, p. 78-80 |
URI: | http://hdl.handle.net/2445/210180 |
Related resource: | https://doi.org/10.1016/j.inoche.2011.11.037 |
ISSN: | 1387-7003 |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
148015.pdf | 499.96 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.