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https://hdl.handle.net/2445/210180| Title: | Synthesis and characterization of CoIII3 inverse metallacrowns via use of 6-methyl-2-pyridylaldoxime |
| Author: | Vlahopoulou, Gina Escuer Fité, Albert Font Bardia, Ma. Mercedes Calvet Pallàs, Maria Teresa |
| Keywords: | Química inorgànica Estructura cristal·lina (Sòlids) Inorganic chemistry Layer structure (Solids) |
| Issue Date: | 2012 |
| Publisher: | Elsevier B.V. |
| Abstract: | The use of 6-methyl-2-pyridylaldoxime (6-mepaoH) in cobalt carboxylate chemistry has yielded metallacrowns with general formula [CoIII3(μ3-O)(O2CMe)3(6-mepao)3]2[CoII(L)4] (1⋅2MeOH⋅1.5H2O, L=AcO−and 2⋅2.5H2O, L=NCS−). Compounds 1 and 2 display an unusual structural motif in cobalt-oximate chemistry, consisting of CoIII triangles centered by one μ3-oxo ligand. Crystal structure and EPR characterization of CoII anions are reported. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2011.11.037 |
| It is part of: | Inorganic Chemistry Communications, 2012, vol. 16, p. 78-80 |
| URI: | https://hdl.handle.net/2445/210180 |
| Related resource: | https://doi.org/10.1016/j.inoche.2011.11.037 |
| ISSN: | 1387-7003 |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) Articles publicats en revistes (Química Inorgànica i Orgànica) |
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