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DC Field | Value | Language |
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dc.contributor.author | Alvarez-Coscojuela, Adrian | - |
dc.contributor.author | Mañosa Bover, Jofre | - |
dc.contributor.author | Formosa Mitjans, Joan | - |
dc.contributor.author | Chimenos Ribera, Josep Ma. | - |
dc.date.accessioned | 2024-04-19T16:03:45Z | - |
dc.date.available | 2024-04-19T16:03:45Z | - |
dc.date.issued | 2024-03-13 | - |
dc.identifier.issn | 2352-7102 | - |
dc.identifier.uri | http://hdl.handle.net/2445/210223 | - |
dc.description.abstract | This study examines the structural evaluation of differently activated kaolins for potential use as supplementary cementitious materials (SCM) or as precursor for alternative cementitious materials (ACM). Chemical activation involved amorphizing the kaolinite structure using varying phosphoric acid concentrations, reaction times, and temperatures. Metakaolin obtained via thermal activation served as a comparison. Inductively Coupled Plasma – Optical Emission Spectroscopy (ICP-OES) characterization of the activating solutions revealed phosphoric acid activation leading to dealumination in kaolinite structures, with temperature emerging as the most significant parameter. X-ray diffraction (XRD) confirmed amorphization, attributed to the dealumination process causing Al loss and creating new Si–O–Si interlayered bonds, as monitored by 29Si magic-angle spinning nuclear magnetic resonance (MAS NMR) tracking the change from Q3 to Q4 environments. Furthermore, pozzolanic activity was assessed through Ca(OH)2 consumption and reaction heat release via modified Chapelle and R3 tests, respectively. Kaolinite subjected to intensive chemical activation exhibited high reactivity and increased specific surface area, indicating its potential as a pozzolanic material. Keywords: Kaolin; Chemical activation; Supplementary cementitious materials; Alternative cementitious materials; Dealumination; Pozzolanic reactivity. | - |
dc.format.extent | 15 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1016/j.jobe.2024.109051 | - |
dc.relation.ispartof | Journal of Building Engineering, 2024, vol. 87, p. 1-15 | - |
dc.relation.uri | https://doi.org/10.1016/j.jobe.2024.109051 | - |
dc.rights | cc-by-nc-nd (c) Alvarez-Coscojuela, Adrian, et al., 2024 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.source | Articles publicats en revistes (Ciència dels Materials i Química Física) | - |
dc.subject.classification | Àcid fosfòric | - |
dc.subject.classification | Materials de construcció | - |
dc.subject.classification | Ciment | - |
dc.subject.other | Phosphoric acid | - |
dc.subject.other | Building materials | - |
dc.subject.other | Cement | - |
dc.title | Structural characterisation and reactivity measurement of chemically activated kaolinite | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 747741 | - |
dc.date.updated | 2024-04-19T16:03:50Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Ciència dels Materials i Química Física) |
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858220.pdf | 5.16 MB | Adobe PDF | View/Open |
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