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Title: | Synthesis, Structural Characterization and Spectroscopic Properties of 1,2-Bis[4-(3,5-dimethyl-1H-pyrazol-1-yl)-2-oxobutyl]benzene |
Author: | Guerrero, Miguel Pons, Josefina Font Bardia, Ma. Mercedes Calvet Pallàs, Maria Teresa Ros, Josep |
Keywords: | Estructura cristal·lina (Sòlids) Cristal·lografia Layer structure (Solids) Crystallography |
Issue Date: | 31-Jan-2011 |
Publisher: | Springer Verlag |
Abstract: | The crystal structure of the title compound C22H30N4O2 H2O (L), has been determined using X-ray diffraction at 293 K. The crystal of 1,2-bis[4-(3,5-dimethyl-1H-pyrazol-1-yl)-2-oxobutyl]benzene is in triclinic crystal system with space group P(-1) (Z = 2), lattice parameters a = 8.225(6) A ° , b= 10.967(6) A ° , c=12.903(6) A ° , V = 1119.1(11) A ° 3. Analyses of single crystals of L, crystallized from dichloromethane/diethyl ether (1:1), revealed that the molecules are arranged in couples, which adopt a pseudo chair conformation, by means of intermolecular O-H N hydrogen bonding interactions. Moreover, the extended structure revealed a 1D chain caused by several C-H N intermolecular interactions. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1007/s10870-010-9960-y |
It is part of: | Journal of Chemical Crystallography, 2011, vol. 41, p. 721-726 |
URI: | http://hdl.handle.net/2445/213300 |
Related resource: | https://doi.org/10.1007/s10870-010-9960-y |
ISSN: | 1074-1542 |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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