Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/216086
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dc.contributor.authorSánchez-Férez, Francisco-
dc.contributor.authorSolans-Monfort, Xavier-
dc.contributor.authorRodríguez-Santiago, Luis-
dc.contributor.authorCalvet Pallàs, Maria Teresa-
dc.contributor.authorFont Bardia, Ma. Mercedes-
dc.contributor.authorPons, Josefina-
dc.date.accessioned2024-10-28T13:24:39Z-
dc.date.available2024-10-28T13:24:39Z-
dc.date.issued2024-02-
dc.identifier.issn0022-4596-
dc.identifier.urihttps://hdl.handle.net/2445/216086-
dc.description.abstractIn this work, two families of Cu(I)-iodide complexes with N-heterocyclic donors ligands bearing amide, phenyl,</p><p>chloro, and methyl substituents have been synthesized to combine two structural directing factors: attractive</p><p>interactions and steric bulkiness. To this aim, we synthesized five Cu(I)-iodide based complexes: two 1D coordination</p><p>polymers [CuI(isn)]n (1) and {[CuI(nic)]⋅ACN}n (2), one tetrameric cubane [CuI(3-phpy)]4 (3), one</p><p>rhomboid dimer [CuI(8-ClQuin)]2 (4) and one monomer [CuI(1-CH3isoQuin)] (5). Interestingly, easy ligand</p><p>dissociation and marked distortions within the molecular structure enabled structural rearrangements between</p><p>the mentioned arrays. Then, we compiled the structures contained in this family of materials and provided a</p><p>shape map and a conversion pathway between the most similar arrays, the cubane and the staircase polymer.</p><p>Finally, the photophysical properties of 1–5 were investigated and electronic transitions were identified and</p><p>supported by DFT and TD-DFT calculations since their photophysical properties are strongly dependent on the</p><p>molecular arrangement and electronic distribution.-
dc.format.extent16 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier-
dc.relation.isformatofReproducció del document publicat a: https://doi.org/https://doi.org/10.1016/j.jssc.2024.124639-
dc.relation.ispartofJournal of Solid State Chemistry, 2024, vol. 333-
dc.relation.urihttps://doi.org/https://doi.org/10.1016/j.jssc.2024.124639-
dc.rightscc-by (c) The Author(s), 2024-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.sourceArticles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)-
dc.subject.classificationCristal·lografia-
dc.subject.classificationLligands-
dc.subject.classificationQuímica inorgànica-
dc.subject.classificationPolímers-
dc.subject.classificationQuímica organometàl·lica-
dc.subject.otherCrystallography-
dc.subject.otherLigands-
dc.subject.otherInorganic chemistry-
dc.subject.otherPolymers-
dc.subject.otherOrganometallic chemistry-
dc.titleStructure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligandsStructure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec751276-
dc.date.updated2024-10-28T13:24:39Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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