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https://hdl.handle.net/2445/216086
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DC Field | Value | Language |
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dc.contributor.author | Sánchez-Férez, Francisco | - |
dc.contributor.author | Solans-Monfort, Xavier | - |
dc.contributor.author | Rodríguez-Santiago, Luis | - |
dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Pons, Josefina | - |
dc.date.accessioned | 2024-10-28T13:24:39Z | - |
dc.date.available | 2024-10-28T13:24:39Z | - |
dc.date.issued | 2024-02 | - |
dc.identifier.issn | 0022-4596 | - |
dc.identifier.uri | https://hdl.handle.net/2445/216086 | - |
dc.description.abstract | In this work, two families of Cu(I)-iodide complexes with N-heterocyclic donors ligands bearing amide, phenyl,</p><p>chloro, and methyl substituents have been synthesized to combine two structural directing factors: attractive</p><p>interactions and steric bulkiness. To this aim, we synthesized five Cu(I)-iodide based complexes: two 1D coordination</p><p>polymers [CuI(isn)]n (1) and {[CuI(nic)]⋅ACN}n (2), one tetrameric cubane [CuI(3-phpy)]4 (3), one</p><p>rhomboid dimer [CuI(8-ClQuin)]2 (4) and one monomer [CuI(1-CH3isoQuin)] (5). Interestingly, easy ligand</p><p>dissociation and marked distortions within the molecular structure enabled structural rearrangements between</p><p>the mentioned arrays. Then, we compiled the structures contained in this family of materials and provided a</p><p>shape map and a conversion pathway between the most similar arrays, the cubane and the staircase polymer.</p><p>Finally, the photophysical properties of 1–5 were investigated and electronic transitions were identified and</p><p>supported by DFT and TD-DFT calculations since their photophysical properties are strongly dependent on the</p><p>molecular arrangement and electronic distribution. | - |
dc.format.extent | 16 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Elsevier | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/https://doi.org/10.1016/j.jssc.2024.124639 | - |
dc.relation.ispartof | Journal of Solid State Chemistry, 2024, vol. 333 | - |
dc.relation.uri | https://doi.org/https://doi.org/10.1016/j.jssc.2024.124639 | - |
dc.rights | cc-by (c) The Author(s), 2024 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
dc.subject.classification | Cristal·lografia | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Química inorgànica | - |
dc.subject.classification | Polímers | - |
dc.subject.classification | Química organometàl·lica | - |
dc.subject.other | Crystallography | - |
dc.subject.other | Ligands | - |
dc.subject.other | Inorganic chemistry | - |
dc.subject.other | Polymers | - |
dc.subject.other | Organometallic chemistry | - |
dc.title | Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligandsStructure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 751276 | - |
dc.date.updated | 2024-10-28T13:24:39Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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869157.pdf | 7.98 MB | Adobe PDF | View/Open |
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