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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/216765
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dc.contributor.authorLópez Martínez, Ma. Concepción-
dc.contributor.authorMoya Álvarez, Carlos-
dc.contributor.authorBasu, Pradipta K.-
dc.contributor.authorGonzález Gazulla, Asensio-
dc.contributor.authorSolans-Monfort, Xavier-
dc.contributor.authorFont Bardia, Ma. Mercedes-
dc.contributor.authorCalvet Pallàs, Maria Teresa-
dc.contributor.authorLalinde, Elena-
dc.contributor.authorMoreno, M. Teresa-
dc.date.accessioned2024-11-27T08:14:21Z-
dc.date.available2024-11-27T08:14:21Z-
dc.date.issued2011-07-27-
dc.identifier.issn0022-2860-
dc.identifier.urihttps://hdl.handle.net/2445/216765-
dc.description.abstractThe study of the reactivity of the 3-methoxyimino-2-phenyl-3H-indoles C6H4-4R1-1-[C8H4N-30-NOMe] [R1 = Cl (1a) or H (1b)] with cis-[PtCl2(dmso)2] has allowed the isolation of trans-[Pt{C6H4-4R1-1- [C8H4N-30-NOMe]}Cl2(dmso)] [R1 = Cl (2a) or H (2b)] and cis-[Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] CH2Cl2 [R1 = Cl (3a) or H(3b)]. Their crystal structures confirm: (a) the existence of a PtANindole bond, (b) the relative arrangement of the Cl ligands (trans in 2a and 2b or cis in 3a and 3b) and (c) the anti- (E) configuration of the oxime. A comparative study of the spectroscopic and photo-optical properties of ligands and their platinum(II) complexes (2a, 2b, 3a and 3b) is also reported.-
dc.format.extent37 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2011.05.030-
dc.relation.ispartofJournal of Molecular Structure, 2011, vol. 999, num.1-3, p. 49-59-
dc.relation.urihttps://doi.org/10.1016/j.molstruc.2011.05.030-
dc.rights(c) Elsevier B.V., 2011-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationCristal·lografia-
dc.subject.classificationLuminescència-
dc.subject.classificationPlatí-
dc.subject.otherCrystallography-
dc.subject.otherLuminescence-
dc.subject.otherPlatinum-
dc.titleSynthesis, crystal structures and properties of cis- and trans-isomers of [Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] (R1 = H or Cl)-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec597819-
dc.date.updated2024-11-27T08:14:21Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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