Please use this identifier to cite or link to this item:
https://hdl.handle.net/2445/217014| Title: | A supramolecular helicate with two independent Fe(ii) switchable centres and a [Fe(anilate)3]3− guest |
| Author: | Barrios Moreno, Leoní Alejandra Teat, Simon J. Roubeau, Olivier Aromí Bedmar, Guillem |
| Keywords: | Òxids Ferro Química supramolecular Oxides Iron Supramolecular chemistry |
| Issue Date: | 2-Aug-2023 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | A biphenyl-spaced bis-pyrazolylpyridine ligand interacts with ferrous ions to engender a dimetallic helical coordination cage that encapsulates an Fe3+ tris-anilate complex. The host–guest interaction breaks the symmetry of the Fe2+ centers causing a differential spin crossover behavior in them that can be followed in great detail crystallographically. |
| Note: | Reproducció del document publicat a: https://doi.org/10.1039/d3cc02278a |
| It is part of: | Chemical Communications, 2023, vol. 59, p. 10628-10631 |
| URI: | https://hdl.handle.net/2445/217014 |
| Related resource: | https://doi.org/10.1039/d3cc02278a |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 833392.pdf | 675.3 kB | Adobe PDF | View/Open |
This item is licensed under a
Creative Commons License
