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Title: | Field-Induced Slow Relaxation of the Magnetization in Two Families of [MIILnIII] Complexes |
Author: | Costa Villén, Ernesto Font Bardia, Ma. Mercedes Mayans Ayats, Júlia Escuer Fité, Albert |
Keywords: | Lantani Propietats magnètiques Lligands Lanthanum Magnetic properties Ligands |
Issue Date: | 3-Jul-2024 |
Publisher: | American Chemical Society |
Abstract: | A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis- (azaneylylidene)) bis(methaneylylidene))bis(benzene-1,2-diol)), obtained from the condensation of ethylenediamine and 2,3-dihydroxybenzaldehyde. All of the complexes have been structurally and magnetically characterized. The dynamic magnetic measurements show that the [CuIILnIII] and [NiIILnIII] derivatives exhibit ac response as a function of the d-cation. Noteworthily, the isotropic GdIII complexes exhibit a slow relaxation of magnetization. |
Note: | Reproducció del document publicat a: https://doi.org/10.1021/acs.cgd.4c00598 |
It is part of: | Crystal Growth & Design, 2024, vol. 24, p. 5806-5817 |
URI: | https://hdl.handle.net/2445/222730 |
Related resource: | https://doi.org/10.1021/acs.cgd.4c00598 |
ISSN: | 1528-7483 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB)) |
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