Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/222730
Title: Field-Induced Slow Relaxation of the Magnetization in Two Families of [MIILnIII] Complexes
Author: Costa Villén, Ernesto
Font Bardia, Ma. Mercedes
Mayans Ayats, Júlia
Escuer Fité, Albert
Keywords: Lantani
Propietats magnètiques
Lligands
Lanthanum
Magnetic properties
Ligands
Issue Date: 3-Jul-2024
Publisher: American Chemical Society
Abstract: A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis- (azaneylylidene)) bis(methaneylylidene))bis(benzene-1,2-diol)), obtained from the condensation of ethylenediamine and 2,3-dihydroxybenzaldehyde. All of the complexes have been structurally and magnetically characterized. The dynamic magnetic measurements show that the [CuIILnIII] and [NiIILnIII] derivatives exhibit ac response as a function of the d-cation. Noteworthily, the isotropic GdIII complexes exhibit a slow relaxation of magnetization.
Note: Reproducció del document publicat a: https://doi.org/10.1021/acs.cgd.4c00598
It is part of: Crystal Growth & Design, 2024, vol. 24, p. 5806-5817
URI: https://hdl.handle.net/2445/222730
Related resource: https://doi.org/10.1021/acs.cgd.4c00598
ISSN: 1528-7483
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Química Teòrica i Computacional (IQTCUB))

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