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http://hdl.handle.net/2445/43586| Title: | Total synthesis of (-)-isoavenaciolide |
| Author: | Santos, David Ariza Piquer, Xavier García Gómez, Jordi Lloyd-Williams, Paul Martínez Laporta, Agustín Sánchez Zarzalejo, Carolina |
| Keywords: | Biomolècules Productes naturals Síntesi asimètrica Medicaments antibacterians Fungicides Biomolecules Natural products Asymmetric synthesis Antibacterial agents Fungicides |
| Issue Date: | 2013 |
| Publisher: | American Chemical Society |
| Abstract: | An enantioselective approach to (-)-isoavenaciolide was achieved starting from 1- undecyn-3-ol. The synthesis relied upon the preparation of a chiral 4-silyloxy-2-alkenylborane by hydroboration of a protected 2,3-allenol and subsequent stereoselective addition to 2- thiophenecarboxaldehyde |
| Note: | Versió postprint del document publicat a: http://dx.doi.org/10.1021/jo302598h |
| It is part of: | Journal of Organic Chemistry, 2013, vol. 78, num. 4, p. 1519-1524 |
| URI: | http://hdl.handle.net/2445/43586 |
| Related resource: | http://dx.doi.org/10.1021/jo302598h |
| ISSN: | 0022-3263 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 619737.pdf | 415.34 kB | Adobe PDF | View/Open |
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