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https://hdl.handle.net/2445/48695| Title: | Preparation of benzolactams by Pd(II)-catalyzed carbonylation of N-unprotected arylethylamines |
| Author: | López Barallobre, Blanca Rodríguez Ramírez, Aleix Santos, David Albert Mach, Joan Ariza Piquer, Xavier García Gómez, Jordi Granell Sanvicente, Jaime Ramón |
| Keywords: | Pal·ladi (Element químic) Química organometàl·lica Reaccions químiques Lactames Imines Palladium Organometallic chemistry Chemical reactions Lactams Imines |
| Issue Date: | 2011 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | An unprecedented NH2-directed Pd(II)-catalytic carbonylation of quaternary aromatic α -amino esters to yield 6-membered 10 benzolactams has been developed. The reaction shows a strong bias to 6-membered lactams over 5-membered ones. The steric hindrance around the amino group seems to be pivotal for the success of the process. |
| Note: | Versió postprint del document publicat a: http://dx.doi.org/10.1039/C0CC03478A |
| It is part of: | Chemical Communications, 2011, vol. 47, p. 1054-1056 |
| URI: | https://hdl.handle.net/2445/48695 |
| Related resource: | http://dx.doi.org/10.1039/C0CC03478A |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 580758.pdf | 456.8 kB | Adobe PDF | View/Open |
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