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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/50467
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dc.contributor.authorAiguabella Font, Núria-
dc.contributor.authorPesquer, Albert-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.contributor.authorRiera i Escalé, Antoni-
dc.date.accessioned2014-02-20T13:16:35Z-
dc.date.available2014-05-28T22:02:23Z-
dc.date.issued2013-05-28-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/2445/50467-
dc.description.abstractA new approach to the synthesis of 4,5-disubstituted cyclopentenones is described. The strategy is based on the Pauson-Khand (PK) reaction of norbornadiene and N-Boc-propargylamine as alkyne with a masked leaving group, which can be eliminated at will. This approach to the synthesis of 4,5-disubstituted cyclopentenones overcomes the problem of using the alkylation to introduce the alpha-side-chain. As an example, prostane 13-epi-12-oxo-phytodienoic acid (13-epi-12-oxo-PDA) methyl ester was synthesized.-
dc.format.extent4 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: http://dx.doi.org/10.1021/ol400999a-
dc.relation.ispartofOrganic Letters, 2013, vol. 15, num. 11, p. 2696-2699-
dc.relation.urihttp://dx.doi.org/10.1021/ol400999a-
dc.rights(c) American Chemical Society , 2013-
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)-
dc.subject.classificationCiclització (Química)-
dc.subject.classificationQuímica biorgànica-
dc.subject.classificationCompostos orgànics-
dc.subject.classificationSíntesi orgànica-
dc.subject.classificationHormones-
dc.subject.classificationEfecte de l'estrès sobre les plantes-
dc.subject.classificationEstrès (Psicologia)-
dc.subject.classificationProstaglandines-
dc.subject.classificationBiomolècules-
dc.subject.otherRing formation (Chemistry)-
dc.subject.otherBioorganic chemistry-
dc.subject.otherOrganic compounds-
dc.subject.otherOrganic synthesis-
dc.subject.otherHormones-
dc.subject.otherEffect of stress on plants-
dc.subject.otherStress (Psychology)-
dc.subject.otherProstaglandins-
dc.subject.otherBiomolecules-
dc.titlePauson-Khand Adducts of N-Boc-propargylamine: A New Approach to 4,5-Disubstituted Cyclopentenoneseng
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec632485-
dc.date.updated2014-02-20T12:18:26Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))

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