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http://hdl.handle.net/2445/54408
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DC Field | Value | Language |
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dc.contributor.author | Aiguabella Font, Núria | - |
dc.contributor.author | Arce, Elsa M. | - |
dc.contributor.author | Pozo, Carlos del | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.date.accessioned | 2014-05-22T11:43:34Z | - |
dc.date.available | 2014-05-22T11:43:34Z | - |
dc.date.issued | 2014-02-03 | - |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.uri | http://hdl.handle.net/2445/54408 | - |
dc.description.abstract | Abstract: The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are preferred in all cases, independently of the electronic properties of the alkyne. The regioselectivity observed with norbornadiene and ethylene is higher than in the case of norbornene. | - |
dc.format.extent | 12 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI Publishing | - |
dc.relation.isformatof | Reproducció del document publicat a: http://doi.dx.org/10.3390/molecules19021763 | - |
dc.relation.ispartof | Molecules, 2014, vol. 19, num. 2, p. 1763-1774 | - |
dc.relation.uri | http://dx.doi.org/10.3390/molecules19021763 | - |
dc.rights | cc-by (c) Aiguabella Font, Núria et al., 2014 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Ciclització (Química) | - |
dc.subject.classification | Química organometàl·lica | - |
dc.subject.classification | Cobalt | - |
dc.subject.other | Ring formation (Chemistry) | - |
dc.subject.other | Organometallic chemistry | - |
dc.subject.other | Cobalt | - |
dc.title | Pauson-Khand reaction of internal dissymmetric trifluoromethyl alkynes. influence of the alkene on the regioselectivity | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 633458 | - |
dc.date.updated | 2014-05-22T11:43:34Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 24496269 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona)) |
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633458.pdf | 237.39 kB | Adobe PDF | View/Open |
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