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DC Field | Value | Language |
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dc.contributor.advisor | Rodríguez Raurell, Laura | - |
dc.contributor.advisor | Alfonso Rodríguez, Ignacio | - |
dc.contributor.author | Sintes Marcos, Miquel | - |
dc.date.accessioned | 2014-07-14T09:35:24Z | - |
dc.date.available | 2014-07-14T09:35:24Z | - |
dc.date.issued | 2014-06 | - |
dc.identifier.uri | http://hdl.handle.net/2445/55774 | - |
dc.description | Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2014, Tutors: Dra. Laura Rodríguez Raurell i Dr. Ignacio Alfonso Rodríguez | ca |
dc.description.abstract | The aim of this work is the synthesis of the chiral pseudopeptidic macrocycle 5b and its use, together with analogue macrocycle 5a (Scheme 1) as ligands for Cu2+, in molecular recognition processes of amino acids. The two dinuclear complexes will be used as receptors in molecular recognition processes. The synthesis of the [2+2] pseudopeptidic macrocycle through a reductive amination is carried out by using an anionic template which places the four subunits in the right orientation for their union. The obtained product is characterized by ESI-MS and NMR. Copper complexes are prepared starting with the meta macrocycle and its para analogue. The resulting products are characterized by ESI MS. A comparative study of many amino acids and analogues behavior with the two macrocyclic complexes is carried out by UV-Vis spectrophotometry. After that, recognition tests are made with the two possible Malate isomers and association constants values are calculated for both isomers with macrocyclic copper complex. | ca |
dc.format.extent | 55 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | ca |
dc.rights | cc-by-nc-nd (c) Sintes Marcos, 2014 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | - |
dc.source | Treballs Finals de Grau (TFG) - Química | - |
dc.subject.classification | Reconeixement molecular | cat |
dc.subject.classification | Química supramolecular | cat |
dc.subject.classification | Treballs de fi de grau | cat |
dc.subject.other | Molecular recognition | eng |
dc.subject.other | Supramolecular chemistry | eng |
dc.subject.other | Bachelor's theses | eng |
dc.title | Metallic pseudopeptidic macrocycles. Study of molecular recognition processes of amino acids | eng |
dc.title.alternative | Macrocicles pseudopeptídics metàl·lics. Estudi de processos de reconeixement molecular d'aminoàcids | cat |
dc.type | info:eu-repo/semantics/masterThesis | ca |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca |
Appears in Collections: | Treballs Finals de Grau (TFG) - Química |
Files in This Item:
File | Description | Size | Format | |
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TFG_QU Sintes_Marcos_Miquel.pdf | 2.14 MB | Adobe PDF | View/Open |
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