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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/68334
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dc.contributor.authorOrgué Gassol, Sílvia-
dc.contributor.authorFlores-Gaspar, Areli-
dc.contributor.authorBiosca, Maria-
dc.contributor.authorPàmies, Oscar-
dc.contributor.authorDiéguez, Montserrat-
dc.contributor.authorRiera i Escalé, Antoni-
dc.contributor.authorVerdaguer i Espaulella, Xavier-
dc.date.accessioned2015-12-04T10:43:32Z-
dc.date.issued2015-10-02-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/2445/68334-
dc.description.abstractThe stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.-
dc.format.extent4 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherRoyal Society of Chemistry-
dc.relation.isformatofReproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a-
dc.relation.ispartofChemical Communications, 2015, vol. 51, p. 17548-17551-
dc.relation.urihttp://dx.doi.org/10.1039/c5cc07504a-
dc.rightscc by (c) Orgué Gassol, Sílvia et al., 2015-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subject.classificationHidròlisi-
dc.subject.classificationLligands-
dc.subject.classificationCatàlisi asimètrica-
dc.subject.classificationCompostos de bor-
dc.subject.otherHydrolysis-
dc.subject.otherLigands-
dc.subject.otherEnantioselective catalysis-
dc.subject.otherBoron compounds-
dc.titleStereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec654578-
dc.date.updated2015-12-04T10:43:32Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
dc.identifier.pmid26477668-
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)
Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona))

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