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http://hdl.handle.net/2445/68334
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DC Field | Value | Language |
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dc.contributor.author | Orgué Gassol, Sílvia | - |
dc.contributor.author | Flores-Gaspar, Areli | - |
dc.contributor.author | Biosca, Maria | - |
dc.contributor.author | Pàmies, Oscar | - |
dc.contributor.author | Diéguez, Montserrat | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.date.accessioned | 2015-12-04T10:43:32Z | - |
dc.date.issued | 2015-10-02 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/2445/68334 | - |
dc.description.abstract | The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands. | - |
dc.format.extent | 4 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a | - |
dc.relation.ispartof | Chemical Communications, 2015, vol. 51, p. 17548-17551 | - |
dc.relation.uri | http://dx.doi.org/10.1039/c5cc07504a | - |
dc.rights | cc by (c) Orgué Gassol, Sílvia et al., 2015 | - |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject.classification | Hidròlisi | - |
dc.subject.classification | Lligands | - |
dc.subject.classification | Catàlisi asimètrica | - |
dc.subject.classification | Compostos de bor | - |
dc.subject.other | Hydrolysis | - |
dc.subject.other | Ligands | - |
dc.subject.other | Enantioselective catalysis | - |
dc.subject.other | Boron compounds | - |
dc.title | Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 654578 | - |
dc.date.updated | 2015-12-04T10:43:32Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 26477668 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona)) |
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File | Description | Size | Format | |
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654578.pdf | 1.41 MB | Adobe PDF | View/Open |
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