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http://hdl.handle.net/2445/99092
Title: | Study of the oligomerization of 1-octene catalyzed by macroreticular ion-exchange resins |
Author: | Bringué Tomàs, Roger Cadenas, Madelin Fité Piquer, Carles Iborra Urios, Montserrat Cunill García, Fidel |
Keywords: | Resines de bescanvi iònic Cinètica enzimàtica Catàlisi Ion exchange resins Enzyme kinetics Catalysis |
Issue Date: | 23-Jul-2012 |
Publisher: | Elsevier B.V. |
Abstract: | Oligomerization of 1-octene is a feasible alternative to improve the properties and the quality of fuels and lubricants oils. The performance of macroreticular ion-exchange resins as catalysts for such reaction has been evaluated. The experimental setup consisted of a batch stirred-tank reactor that operated at 353-393 K and 2 MPa. 1-Octene conversion was practically complete and the selectivity to double-bond isomerization and dimers after 6 h at 373 K was up to 95% and 12%, respectively. The accessible acidity of the catalysts was the most important structural parameter for these reactions. Selectivity to dimers and branched isomers increased with increasing temperature. Cracking compounds were not detected at all. The theoretical equations derived from the proposed kinetic model fit well the experimental results. |
Note: | Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.cej.2012.06.089 |
It is part of: | Chemical Engineering Journal, 2012, vol. 207-208, p. 226-234 |
URI: | http://hdl.handle.net/2445/99092 |
Related resource: | http://dx.doi.org/10.1016/j.cej.2012.06.089 |
ISSN: | 1385-8947 |
Appears in Collections: | Articles publicats en revistes (Enginyeria Química i Química Analítica) |
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