# name
Study of Cu-ZnO-Ga2O3- and MoxC-based Catalysts for the Reverse Water Gas Shift Reaction

# metadata.dc.contributor.other[].value
Universitat de Barcelona. Departament de Química Inorgànica i Orgànica

# metadata.dc.description.abstract[].value
[eng]  Nowadays, serious concern exists about atmospheric CO2 increase related with environmental impact and climate change. The reuse of CO2 through its chemical recycling is a promising route, which could contribute to the decrease of globally emitted CO2. Today CO2 is not only considered a waste, CO2 can be also conveniently used as raw material for industrial applications, and the development of new or improved processes for its use can contribute for a sustainable development. CO2 is a molecule which is thermodynamically stable, and its activation requires high energy input to overcome the energy barrier for the dissociation of C=O bond. However, CO2 can be selectively activated in the presence of H2 through catalytic processes, under appropriate conditions of pressure and temperature. In this doctoral research project, the main objective is related with the development of new catalysts for efficient CO2 conversion to CO via the reverse water gas shift reaction (RWGS) under mild conditions. For such purposes, new multicomponent CuZnOGa2O3MxOy (M=Al, Zr) and MoxC-based catalysts were prepared, deeply characterized and studied under different experimental conditions in the RWGS reaction. CuZnxGaM (M=Al, Zr) catalysts were prepared using a surfactant-free sol-gel method. CuZnxGaZr showed higher surface area, easier reducibility of CuO and a higher amount of surface Cu, Zn and Ga species than CuZn and CuZnxGaAl. Reduced catalysts were highly performant in the RWGS reaction at 250-270 °C, 3 MPa using a CO2/H2/N2=1/3/1 reactant mixture. CuZnxGaZr were more active than CuZn and CuZnxGaAl catalysts. This is related with a synergetic effect of Cu and the oxygen vacancies at the Cu-Support interface. The RWGS reaction carried out at atmospheric pressure using a CO2/H2/N2=1/3/1 reactant mixture over the CuZn3GaZr, resulted in a CO selectivity close to 100% at 325 °C under a CO2 conversion of 16.8%. The apparent Ea determined in the 275-325 °C range for CO production over CuZn3GaZr catalyst was 70.9±3.7 kJ/mol. On the other hand, new MoxC-based catalysts were prepared using sol-gel routes with different carbon precursors and without additional H2 and/or CH4 reducing thermal treatment. Bulk MoxC catalysts (MoxC-U, MoxC-CA and MoxC-E), gamma-Al2O3-, TiO2-, SBA-15- and SiO2-supported MoxC-U catalysts and, Cu- and Co-modified MoxC-U and MoxC/gamma-Al2O3 catalysts have been studied in the RWGS (CO2/H2/N2=1/3/1 and CO2/H2/N2=1/3/1) reaction in the 275-400 °C range and atmospheric pressure. MoxC-CA having hcp-Mo2C, fcc-Mo2C and/or fcc-MoC and the highest SBET (14.5 m2/g) showed the best performance. A CO yield of 41.8 mol/Kgcat•h, with 98% selectivity to CO was obtained at 400 °C using a CO2/H2/N2=1/3/1 mixture. The apparent Ea determined in the 275-325 °C range for CO production was 64.8+/-4.1 kJ/mol. MoxC-U showed only the presence of polycrystalline hcp-Mo2C. Its characteristics and catalytic properties were deeply analyzed and successfully interpreted in the light of theoretical studies carried out under a collaborative work. The adsorption heat of CO2 on MoxC-U was -3.2 eV. Over hcp-Mo2C, CO2 dissociates at 35 °C to CO+O surface species. Under RWGS conditions, the reaction proceeded by subsequent hydrogenation, and CO and H2O formation. Over MoxC-U, using a CO2/H2/N2=1/1/3 reactant mixture, the CO selectivity at 400 °C, 0.1 MPa, was 99.5% (CO2 conversion=16%). An apparent Ea of 55.2+/- 2.3 kJ/mol for CO production was determined for this catalyst in the 275-325 °C range. Different MoxC phases were obtained in gamma-Al2O3-, TiO2-, SBA-15- and SiO2-supported MoxC-U catalysts as a function of the support. In general, for supported MoxC catalysts, a higher CO production (mol CO/mol Mo•h) when compared with that of MoxC-U was found. 25MoxC/SiO2 catalyst, which showed the presence of hcp-Mo2C and fcc-MoC, was the most performant for CO production; it produced 17.0 mol CO/mol Mo•h at 400 °C, 0.1 MPa and CO2/H2/N2=1/3/1. Using a CO2/H2/N2=1/1/3 reaction mixture, the CO yield was up to 5 times higher than that obtained over the bulk MoxC-U catalyst.

# metadata.dc.description.abstract[].value
[spa]  El reciclado de CO2 mediante su uso como reactivo en determinados procesos puede representar una vía que contribuya a su reducción en la atmósfera. La molécula de CO2 es termodinámicamente muy estable, sin embargo, se puede conseguir su activación mediante el uso de catalizadores apropiados, y su posterior transformación a productos de interés mediante diferentes procesos. Entre ellos, la reacción de desplazamiento inversa de agua (RWGS, de su acrónimo en inglés) representa una ruta atractiva. El desarrollo de nuevos catalizadores para este proceso es por tanto de interés actual. En esta tesis doctoral se han desarrollado nuevos catalizadores basados en sistemas multicomponentes CuZnOGa2O3MxOy (M=Al, Zr) y en MoxC. Se han caracterizado, y analizado su comportamiento catalítico en la RWGS bajo diversas condiciones de reacción y usando diferentes mezclas de reactivos, CO2/H2/N2=1/3/1 y CO2/H2/N2=1/1/1. Los catalizadores CuZnOGa2O3MxOy (M=Al, Zr) se han preparado mediante un método sol-gel sin el empleo de surfactante. Los catalizadores reducidos CuZnxGaZr, resultaron los más activos en la RWGS. A presión atmosférica y utilizando una mezcla reactante CO2/H2/N2=1/3/1, el catalizador CuZn3GaZr presentó una selectividad hacia CO de prácticamente el 100% a 325 °C bajo una conversión de CO2 del 16.8%. La energía de activación aparente determinada para este catalizador en el rango de 275-325 °C fue de 70.9±3.7 kJ/mol. Por otra parte, los sistemas basados en MoxC se han preparado mediante rutas sol-gel empleando diferentes precursores de carbono y sin el uso adicional de tratamientos térmicos con H2 o CH4. Así, se prepararon catalizadores másicos (MoxC-U, MoxC-CA and MoxC-E) y MoxC-U soportado en gamma-Al2O3, TiO2, SBA-15 y SiO2. Entre los catalizadores másicos, el MoxC-CA mostró el mejor comportamiento catalítico, con una producción de CO de 41.8 mol/Kgcat•h, con selectividad a CO del 98% a 400 °C y utilizando una mezcla de reacción CO2/H2/N2=1/3/1. La energía de activación aparente determinada en el rango 275-325 °C fue de 64.8+/-4.1 kJ/mol. El catalizador MoxC-U presentó exclusivamente la presencia de la fase policristalina hcp-Mo2C. Sus características y propiedades catalíticas pudieron ser convenientemente interpretadas en base a resultados de estudios teóricos realizados en un trabajo en colaboración. Los catalizadores soportados mostraron, en general, mayores producciones de CO (mol CO/mol Mo•h) que el correspondiente catalizador másico (MoxC-U).

# metadata.dc.source[].value
Tesis Doctorals - Departament - Química Inorgànica i Orgànica

# metadata.dc.subject.classification[].value
Captura i emmagatzematge de diòxid de carboni

# metadata.dc.title[].value
Study of Cu-ZnO-Ga2O3- and MoxC-based Catalysts for the Reverse Water Gas Shift Reaction