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Lithium cations in a self-assembled electrostatic nanocapsule

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Cascade self-assembly of small components, without the employment of preformed hosts, yielded a {Ni12Li2} nanometric capsule with multiple endo- and exo-guests (water molecules, Li+, and Et3NH+ cations) linked to selective hydrophilic and hydrophobic binding sites of NiII hexanuclear metallamacrocycles. The synthesis was achieved by using (Bu4N)N3 as a starting reagent instead of the conventional sodium azide to selectively introduce the Li+ cations.

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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Lithium cations in a self-assembled electrostatic nanocapsule