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Towards the tailored design of benzotriazinyl-based organic radicals displaying a spin transition

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The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl- 1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of radicals, and how those can be exploited by a rational design of the spin-carrying units.

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Articles publicats en revistes (Ciència dels Materials i Química Física)

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Towards the tailored design of benzotriazinyl-based organic radicals displaying a spin transition